5341-14-0 Usage
Uses
Used in Organic Synthesis:
TRIS(4-BIPHENYL)-METHANOL is used as a phase-transfer catalyst for increasing the reaction rate and yield in organic synthesis processes. Its ability to transfer reactants or ions between phases makes it a crucial component in various chemical reactions.
Used in Asymmetric Synthesis:
In the field of asymmetric synthesis, TRIS(4-BIPHENYL)-METHANOL is used as a chiral auxiliary, which aids in the production of enantiomerically pure compounds. This application is particularly important in the pharmaceutical industry, where the purity of enantiomers can significantly impact the effectiveness and safety of drugs.
Used in Pharmaceutical Industry:
TRIS(4-BIPHENYL)-METHANOL is used as a key component in the synthesis of complex molecular structures, which are often required for the development of new pharmaceuticals. Its role in asymmetric synthesis ensures that the final products have the desired chiral purity, which is essential for their therapeutic effects and to minimize potential side effects.
Check Digit Verification of cas no
The CAS Registry Mumber 5341-14-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,3,4 and 1 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 5341-14:
(6*5)+(5*3)+(4*4)+(3*1)+(2*1)+(1*4)=70
70 % 10 = 0
So 5341-14-0 is a valid CAS Registry Number.
InChI:InChI=1/C37H28O/c38-37(34-22-16-31(17-23-34)28-10-4-1-5-11-28,35-24-18-32(19-25-35)29-12-6-2-7-13-29)36-26-20-33(21-27-36)30-14-8-3-9-15-30/h1-27,38H
5341-14-0Relevant academic research and scientific papers
Heterobifunctional Rotaxanes for Asymmetric Catalysis
Daniliuc, Constantin G.,Grimme, Stefan,Huber, Alexander,Jansen, Dennis,Niemeyer, Jochen,Pairault, No?l,Zhu, Hui
supporting information, p. 5102 - 5107 (2020/01/25)
Heterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine-based thread and a chiral 1,1′-binaphthyl-phosphoric-acid-b
Tungsten-catalyzed asymmetric epoxidation of allylic and homoallylic alcohols with hydrogen peroxide
Wang, Chuan,Yamamoto, Hisashi
supporting information, p. 1222 - 1225 (2014/02/14)
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant, yielding the products in 84-98% ee.
Template synthesis of [2]rotaxanes with large ring components and tris(biphenyl)methyl group as the blocking group. The relationship between the ring size and the stability of the rotaxanes
Saito, Shinichi,Nakazono, Kazuko,Takahashi, Eiko
, p. 7477 - 7480 (2007/10/03)
We synthesized a series of macrocyclic phenanthrolines 3a-e and a tris(biphenyl)methyl derivative 4. [2]Rotaxanes with large ring components (10a,b) were synthesized by the template method, and the stability of the rotaxanes was examined. The study reveal
