5341-14-0

Basic information

• Product Name: TRIS(4-BIPHENYL)-METHANOL
• Synonyms: TRIS(4-BIPHENYL)-METHANOL
• CAS NO: 5341-14-0
• Molecular Formula: C₃₇H₂₈O
• Molecular Weight: 488.61762
• Mol File: 5341-14-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 671°C at 760 mmHg
• Flash Point: 214.6°C
• Appearance: /
• Density: 1.146g/cm³
• Vapor Pressure: 6.36E-19mmHg at 25°C
• Refractive Index: 1.646
• CAS DataBase Reference: TRIS(4-BIPHENYL)-METHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS(4-BIPHENYL)-METHANOL(5341-14-0)
• EPA Substance Registry System: TRIS(4-BIPHENYL)-METHANOL(5341-14-0)

Safety Data

• Hazardous Substances Data: 5341-14-0(Hazardous Substances Data)

Usage

General Description

TRIS(4-BIPHENYL)-METHANOL is a chemical compound that is commonly used as a phase-transfer catalyst in organic synthesis. It is known for its ability to facilitate the transfer of a reactant or an ion from one phase to another, thereby increasing the reaction rate and yield. TRIS(4-BIPHENYL)-METHANOL is also used as a chiral auxiliary in asymmetric synthesis, allowing for the production of enantiomerically pure compounds. TRIS(4-BIPHENYL)-METHANOL is a versatile and valuable tool in synthetic organic chemistry, enabling the efficient and selective formation of complex molecular structures.

InChI:InChI=1/C37H28O/c38-37(34-22-16-31(17-23-34)28-10-4-1-5-11-28,35-24-18-32(19-25-35)29-12-6-2-7-13-29)36-26-20-33(21-27-36)30-14-8-3-9-15-30/h1-27,38H

Upstream product

• 91-66-7 N,N-diethylaniline 
• 2051-62-9 4'-biphenyl chloride 
• 105-58-8 Diethyl carbonate 
• 71-43-2 benzene 
• 60-29-7 diethyl ether 
• 64-17-5 ethanol 
• 92-67-1 4-phenylalanine 
• 64295-54-1 4,4',4''-triphenyl-trityl chloride 
• 3478-90-8 4,4'-diphenylbenzophenone 
• 1591-31-7 4-iodo-biphenyl 
• 92-93-3 1-phenyl-4-nitrobenzene 
• 3315-91-1 4-biphenylylmagnesium bromide 
• 92-66-0 4-bromo-1,1'-biphenyl 

Downstream Products

• 60916-59-8 tris(p-phenylphenyl)methyl bromide 
• 13620-21-8 N--toluol-4-sulfonamid 
• 1541181-14-9 C₃₉H₂₉ClO 
• 13561-38-1 N--benzol-sulfonamid 
• 872813-71-3 (4,4',4''-triphenyl-trityl)-phosphonic acid-dichloride 
• 103399-52-6 tris(1,1'-biphenyl-4-yl)methane 
• 64295-54-1 4,4',4''-triphenyl-trityl chloride 
• 907157-71-5 1,1,1-tris(1,1'-biphenyl-4-yl)-7-iodoheptane 
• 907157-70-4 7,7,7-tris(1,1'-biphenyl-4-yl)-1-heptanol 

Relevant articles and documents

Heterobifunctional Rotaxanes for Asymmetric Catalysis

Heterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine-based thread and a chiral 1,1′-binaphthyl-phosphoric-acid-b

Template synthesis of [2]rotaxanes with large ring components and tris(biphenyl)methyl group as the blocking group. The relationship between the ring size and the stability of the rotaxanes

We synthesized a series of macrocyclic phenanthrolines 3a-e and a tris(biphenyl)methyl derivative 4. [2]Rotaxanes with large ring components (10a,b) were synthesized by the template method, and the stability of the rotaxanes was examined. The study reveal