53492-34-5

Usage

InChI:InChI=1/C20H24O4/c1-15(9-19-10-17(3)12-23-19)5-4-6-16(2)11-20(21)24-14-18-7-8-22-13-18/h5,7-8,10-13H,4,6,9,14H2,1-3H3/b15-5+,16-11+

Upstream product

• 4412-91-3 furan-3-methanol 
• 78259-66-2 (E,E)-3,7-dimethyl-8-(4-methyl-2-furyl)octa-2,6-dienoic acid 
• 66408-80-8 (2E,6E)-2,6-dimethyl-8-((tetrahydro-2H-pyran-2-yl)oxy)octa-2,6-dien-1-ol 
• 38290-55-0 2-<(2E,6E)-8-bromo-3,7-dimethylocta-2,6-dien-1-yloxy>tetrahydro-2H-pyran 
• 78259-59-3 2-Bromo-4-methyl-furan 
• 78259-64-0 2-[(2E,6E)-3,7-Dimethyl-8-(4-methyl-furan-2-yl)-octa-2,6-dienyloxy]-tetrahydro-pyran 
• 78259-65-1 methyl (E,E)-3,7-dimethyl-8-(4-methyl-2-furyl)octa-2,6-dienoate 
• 78259-67-3 (2E,6E)-3,7-Dimethyl-8-(4-methyl-furan-2-yl)-octa-2,6-dienal 
• 78259-63-9 2-<(E,E)-2,6-dimethyl-8-hydroxyocta-2,6-dienyl>-4-methylfuran 
• 2528-01-0 5-bromo-3-methylfuran-2-carboxylic acid methyl ester 
• 5896-35-5 5-bromo-3-methylfuran-2-carboxylic acid 
• 59632-99-4 geranyl 2-tetrahydropyranyl ether 
• 6141-57-7 methyl 3-methylfuran-2-carboxylate 
• 78284-85-2 marislin 

Relevant academic research and scientific papers

General Routes to 4-Methyl-2-substituted-furans: a Total Synthesis of Pleraplysillin-2, a Metabolite of the Sponge, Pleraplysilla spinifera

A general approach to 4-methyl-2-substituted-furans is described in which 4-methyl-2-furyl-lithium is the key intermediate.Using this method, pleraplysillin-2, a sesquiterpenoid ester from the sponge Pleraplysilla spinifera, has been synthesised.An alternative, less efficient, route to this type of furan, via acyclic keto-epoxides, is also discussed.

CHEMICAL CONSTITUENTS OF THE NUDIBRANCH CHROMODORIS MARISLAE

The major metabolite of Chromodoris marislae, marislin (1a) was identif ied from spectral data and converted into the sponge metabolite pleraplysillin-2 (lb).