53545-93-0Relevant academic research and scientific papers
TOTAL SYNTHESIS OF THE AMARYLLIDACEAE ALKALOID (+/-)-EPIELWESINE. THE IMPORTANCE OF VINYLSILANE STEREOCHEMISTRY IN IMINIUM ION-VINYLSILANE CYCLIZATIONS
Burk, Robert M.,Overman, Larry E.
, p. 205 - 225 (2007/10/02)
(+/-)-Epielwesine (9) was prepared in an efficient and completely stereocontrolled fashion in six steps and 28percent overall yield from commercially available 3,4-methylenedioxyphenylacetonitrile (15a).The key step is acid promoted cyclization of the (Z)
A CONVENIENT SYNTHESIS OF Δ1-PYRROLINES AND Δ1-PIPERIDEINES
Overman, Larry E.,Burk, Robert M.
, p. 5737 - 5738 (2007/10/02)
Imines 5 are formed in excellent yield from the reaction of nitriles 2 with diisobutylaluminium hydride.
