53662-83-2

Basic information

• Product Name: 2,5-FURANDICARBOXYLIC ACID DIETHYL ESTER
• Synonyms: 2,5-FURANDICARBOXYLIC ACID DIETHYL ESTER;Furan-2,5-dicarboxylic Acid Diethyl Ester;Diethyl furan-2,5-dicarboxylate;2,5-Furandicarboxylic acid, 2,5-diethyl ester;Diethyl 2,5-furandicarboxylate
• CAS NO: 53662-83-2
• Molecular Formula: C₁₀H₁₂O₅
• Molecular Weight: 212.19928
• Product Categories: Heterocyclic Compounds;Heterocycles
• Mol File: 53662-83-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 167-1680C/15Torr
• Flash Point: 136 °C
• Appearance: /
• Density: 1.172 g/cm³
• Vapor Pressure: 0.00106mmHg at 25°C
• Refractive Index: 1.479
• Storage Temp.: 2-8°C
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 2,5-FURANDICARBOXYLIC ACID DIETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-FURANDICARBOXYLIC ACID DIETHYL ESTER(53662-83-2)
• EPA Substance Registry System: 2,5-FURANDICARBOXYLIC ACID DIETHYL ESTER(53662-83-2)

Safety Data

• Hazardous Substances Data: 53662-83-2(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

2,5-Furandicarboxylic Acid Diethyl Ester (cas# 53662-83-2) is a compound useful in organic synthesis.

InChI:InChI=1/C10H12O5/c1-3-13-9(11)7-5-6-8(15-7)10(12)14-4-2/h5-6H,3-4H2,1-2H3

Upstream product

• 67-47-0 5-hydroxymethyl-2-furfuraldehyde 
• 64-17-5 ethanol 
• 74-85-1 ethene 
• 4282-32-0 furan-2,5-dicarboxylic acid dimethyl ester 
• 91547-65-8 4-deoxy-L-erythro-5-hexoseulose uronic acid 

Downstream Products

• 3238-40-2 furan-2,5-dicarboxylic acid 
• 1323764-39-1 diethyl 3-cyano-4-(4-cyanophenyl)furan-2,5-dicarboxylate 
• 1323764-36-8 diethyl 3-[(4-cyanophenyl)(hydroxy)methyl]-4-(methylsulfanyl)furan-2,5-dicarboxylate 
• 26095-97-6 furan-2,5-dicarboxylic acid dihydrazide 

Relevant articles and documents

Method for preparation of 2, 5-furandicarboxylic acid diester compound from 5-hydroxymethylfurfural

The invention discloses a method for preparation of a 2, 5-furandicarboxylic acid diester compound from 5-hydroxymethylfurfural. The method uses a cheap and specific non-noble metal as the catalyst, and adopts cheap and easily available oxygen or air as an oxygen source to prepare high purity dimethyl furan-2, 5-dicarboxylate at high efficiency under mild reaction conditions, thus solving the problems of low reaction efficiency, low product yield, high cost and the like in the prior art, and has good application prospects.

METHODS FOR PREPARING 2,5-FURANDICARBOXYLIC ACID

Provided are methods of producing 2,5-furandicarboxylic acid (FDCA) from renewable sources such as seaweed, alginate, oligoalginate, pectin, oligopectin, polygalacturonate, galacturonate, and/or oligogalacturonate. The sugars in the renewable sources can be converted into one or more intermediates such as 4-deoxy-L-erythro-5- hexoseulose uronate (DEHU), 4-deoxy-L-threo-5-hexosulose uronate (DTHU), 5- hydroxymethyl furfural (HMF), 2,5-dihydroxymethyl furan (DHMF), and 5-formyl-2- furancarboxylic acid (FFA), which can be converted into FDCA by dehydration and cyclization to produce 5-formyl-2-furancarboxylic acid (FFA), followed by oxidation to produce FDCA. DEHU or DTHU may also be converted into FDCA by oxidation to produce 2,3-dihydroxy-5-oxohexanedioic acid (DOHA), which then undergoes dehydration and cyclization to produce FDCA.