53676-17-8

Upstream product

• 367-12-4 2-fluorophenol 

Downstream Products

• 704-69-8 Phosphorsaeure-mono-<2-fluor-phenylester> 
• 101155-32-2 2,3-O-isopropylidene-β-D-ribofuranose cyclic 1,5-(2-fluorophenyl)phosphate 
• 1240379-68-3 2-FC₆H₄OP(O)(NHBn)2 
• 1432474-89-9 (E)-ethyl 3-(2-((dimethoxyphosphoryl)oxy)-3-fluorophenyl)acrylate 
• 1432475-03-0 2-fluorophenyl methyl hydrogen phosphate 
• 101155-42-4 Phosphoric acid (3aR,4R,6S,6aR)-2,2-dimethyl-6-(6-piperidin-1-yl-purin-9-yl)-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 2-fluoro-phenyl ester; compound with triethyl-amine 
• 101155-40-2 Phosphoric acid (3aR,4R,6R,6aR)-6-(4-ethoxy-5-methyl-pyrimidin-2-yloxy)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 2-fluoro-phenyl ester; compound with triethyl-amine 
• 101155-36-6 triethylammonium salt of 1-<5-O-(2-fluorophenyl)phosphono-2,3-O-isopropylidene-α-D-ribofuranosyl>-5,6-dimethylbenzimidazole 
• 101155-38-8 Phosphoric acid (3aR,4R,6S,6aR)-6-(3,5-dimethyl-pyrazol-1-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ylmethyl ester 2-fluoro-phenyl ester; compound with triethyl-amine 

Relevant academic research and scientific papers

Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C-H activation. The Royal Society of Chemistry 2013.

New phosphoroamidate compounds: Synthesis, structural characterization and studies on ZnCl2 assisted hydrolysis of the P-N bond

A variety of phosphorodiamidate compounds were synthesized from the corresponding phosphorodichloridate intermediates and phosphorus oxychloride. These were completely characterized using different spectroscopic methods and single crystal X-ray diffraction studies on one of them. Studies revealed that water in the presence of a mild Lewis acid like ZnCl2 was found to assist the hydrolysis of the P-N linkage. The proof of this concept was effectively realized through the hydrolysis of hexamethylphosphoramide.