5368-63-8

Upstream product

• 93214-18-7 exo-6-Phenyl-2-oxabicyclo<3.1.0>hexane 
• 93214-18-7 endo-6-Phenyl-2-oxabicyclo<3.1.0>hexane 
• 1026934-53-1 ((E)-4-Phenyl-but-3-enyloxy)-acetyl chloride 
• 65805-36-9 3-(2-iodoethoxy)prop-1-ene 
• 100-58-3 phenylmagnesium bromide 
• 144849-50-3 Ethyl (4-Phenylbut-3-enyloxy)acetate 
• 144849-55-8 (E)-(4-Phenylbut-3-enyloxy)acetic acid 
• 937-58-6 (3E)-4-phenyl-3-buten-1-ol 
• 6285-99-0 (+/-)-α-benzylidene-γ-butyrolactone 
• 100-52-7 benzaldehyde 
• 68975-07-5 3-benzyltetrahydrofuran-2-one 
• 109-99-9 tetrahydrofuran 
• 173310-28-6 3-benzyltetrahydrofuran-2-ol 
• 86553-36-8 Toluene-4-sulfonic acid 2-((E)-3-phenyl-allyloxy)-ethyl ester 

Downstream Products

• 86553-38-0 1-[(4-methylphenyl)sulfonyl]-2-benzylpyrrolidine 

Relevant academic research and scientific papers

Iron-catalyzed tandem cyclization and cross-coupling reactions of iodoalkanes and aryl grignard reagents

A range of arylmethyl-substituted pyrrolidines and tetrahydrofurans were produced by FeCl2-catalyzed tandem cyclization and cross-coupling reactions of alkyl iodides and aryl Grignard reagents. The substituents on alkenes had a profound effect

Reduction of carboxylic esters to ethers with triethyl silane in the combined use of titanium tetrachloride and trimethylsilyl trifluoromethanesulfonate

Aliphatic acyclic and cyclic ethers are prepared on treatment of their corresponding carboxylic esters and lactones with triethylsilane in the presence of titanium tetrachloride and trimethylsilyl trifluoromethanesulfonate.

Tungsten(0) alkylidene complexes stabilized as pyridinium ylides: New aspects of their synthesis and reactivity

The interaction of dihydropyridines with alkoxycarbene complexes of tungsten has been shown to lead to pyridinium ylid complexes: this transformation has now been applied to the synthesis of a hydroxyl-containing ylid complex by ring-opening of the pentacarbonyl (2-oxacyclopentylidene) tungsten(0) complex and to the synthesis of a series of chiral ylid complexes both from chiral and non-chiral carbene complexes by the use of dihydropyridines and dihydronicotines, respectively. The transfer of the alkylidene moiety of these complexes to nucleophilic olefins will be outlined and discussed. Especially relevant is the interaction of these pyridinium ylid complexes with unsaturated substrates such as dihydropyridines, enamines, and β-alkoxy bis(trimethyl-silyl) ketene acetals. This latter reaction leads to conjugated carboxylic acids, and has been be applied to a new synthesis of a honey bee pheromone, the queen substance.

Aryloxymethyl Radical Cyclizations Mimicking Biological C-C Bond Formation to Methoxy Groups

Attention is drawn to a small group of diverse natural products whose biosynthesis is unusual in involving formation of O-heterocyclic rings by C-C bond formation to aromatic methoxy groups, in net oxidative and non-oxidative processes.It is shown that ar

CYCLODESHYDRATION DE DIOLS EN PRESENCE D'HMPT1

1,4 and 1,5-diols heated with 0.3 equivalent of HMPA undergo cyclodehydration leading to tetrahydrofurans and tetrahydropyrans.

Stereochemical Assignment of the 6-Phenyl-2-oxabicyclohexanes

Preparation and stereochemical assignments of the 6-phenyl-2-oxabicyclohexanes are reported.The stereochemical assignments are based on chemical as well as nmr data.

A RADICAL DEOXYGENATION OF PRIMARY ALCOHOLS BY USE OF TRI-n-BUTYLTIN HYDRIDE - SODIUM IODIDE, AND ITS APPLICATION TO A RADICAL CYCLIZATION

Primary alcohols are deoxygenated to hydrocarbons via tosylates with tri-n-butyltin hydride-sodium iodide under mild radical conditions; the method is useful for the preparation of cyclic compounds from acyclic ones possessing primary hydroxyl and olefinic groups by reductive cyclization.