53716-14-6Relevant articles and documents
Chemoselective reduction of the phosphoryl bond of O-alkyl phosphinates and related compounds: An apparently impossible transformation
Kenny, Niall P.,Rajendran, Kamalraj V.,Gilheany, Declan G.
, p. 16561 - 16564 (2015/11/18)
A method is reported for the phosphoryl bond cleavage of O-alkyl phosphinates, phosphinothioates and certain phosphonamidates to furnish the corresponding P(iii) borane adducts. The two-step procedure relies upon initial activation of the phosphoryl bond with an alkyl triflate, followed by reduction of the resulting intermediate using lithium borohydride.
Esterification of phosphonic and phosphinic acid analogues of glutamic and aspartic acids with ethyl orthoformate - Scope and limitations of the method
Zymanczyk-Duda, Ewa,Lejczak, Barbara,Kafarski, Pawel
, p. 47 - 55 (2007/10/03)
Reaction of C-ethyl esters of phosphonic- and phosphinic acid analogues of glutamic and aspartic acids with ethyl orthoformate provides the mixtures of N-formylamino- and N-ethoxymethyleneimino-derivatives with nearly quantitative yields. Scope and limitations of this procedure were studied by means of GC/MS technique.
