5375-55-3Relevant academic research and scientific papers
Manganese(III) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles
Zhang, Yaxing,Dong, Jianyu,Liu, Lixin,Liu, Long,Zhou, Yongbo,Yin, Shuang-Feng
, p. 2897 - 2901 (2017)
Mn-Catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles is disclosed, which enables the synthesis of a broad range of secondary amides in moderate to excellent yields under mild conditions. The interaction between Mn(iii) and DDQ facilitates the oxidation and makes it highly efficient and selective.
