53929-39-8

Upstream product

• 58650-53-6 benzyl endo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 100-51-6 benzyl alcohol 
• 93173-32-1 2,4,6-tri-O-acetyl-3-O-allyl-α-D-glucopyranosyl bromide 
• 103078-10-0 benzyl 2,4,6-tri-O-acetyl-3-O-allyl-β-D-glucopyranoside 
• 103130-09-2 benzyl 3-O-allyl-β-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 100-39-0 benzyl bromide 
• 103078-11-1 benzyl 3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 14897-54-2 benzyl 2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 106-95-6 allyl bromide 

Downstream Products

• 103130-11-6 benzyl 3-O-allyl-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-16-6 benzyl 3-O-(3-allyl-β-D-glucopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-17-7 benzyl 3-O-(3-O-allyl-4,6-O-benzylidene-β-D-glucopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-20-2 benzyl 2,4,6-tri-O-benzyl-3-O-(2,4-di-O-benzyl-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 103078-15-5 benzyl 2,4,6-tri-O-benzyl-3-O-(2,4,6-tri-O-acetyl-3-O-allyl-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 103078-19-9 benzyl 3-O-(3-O-allyl-2,4-di-O-benzyl-β-D-glucopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-18-8 benzyl 3-O-(3-O-allyl-2-O-benzyl-4,6-O-benzylidene-β-D-glucopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-22-4 benzyl-2,4,6-tri-O-benzyl-3-O-(2,4,6-tri-O-benzyl-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 103078-21-3 benzyl 3-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-glucopyranosyl)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103078-14-4 benzyl 2,4-di-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 103078-13-3 benzyl 3-O-allyl-2,4-di-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 103078-26-8 benzyl O-β-D-glucopyranosyl-(1-3)-O-<β-D-glucopyranosyl-(1-6)>-O-(2,4-di-O-benzyl-β-D-glucopyranosyl)-(1-3)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 103130-10-5 benzyl 2,4-di-O-benzyl-β-D-glucopyranoside 
• 103130-13-8 benzyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

SYNTHESIS OF THE REPEATING UNITS OF SCHIZOPHYLLAN

The tetrasaccharides β-D-Glcp-(1-3)-β-D-Glcp-(1-3)--D-Glcp, β-D-Glcp-(1-3)--β-D-Glcp-(1-3)-D-Glcp, and β-D-Glcp-(1-6)-β-D-Glcp-(1-3)-β-D-Glcp-(1-3)-D-Glcp, corresponding to the three possible repeating-units of Schizophylla

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga