5395-08-4Relevant articles and documents
Graphitic carbon nitride catalysed photoacetalization of aldehydes/ketones under ambient conditions
Abdullah Khan,Teixeira, Ivo F.,Li, Molly M. J.,Koito, Yusuke,Tsang, Shik Chi Edman
supporting information, p. 2772 - 2775 (2016/02/18)
Graphitic-C3N4 is shown for the first time to catalyse photoacetalization of aldehydes/ketones with alcohols to acetals in high yields using visible light under ambient conditions; transient charge separation over the material is effective to catalyse the reaction in the absence of Lewis or Br?nsted acids, giving a new green alternative catalyst.
Method for synthesizing bis-ether compound by catalyzing benzaldehyde through mixed type heteropoly acid
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Paragraph 0015; 0016, (2017/05/18)
The invention discloses a method for synthesizing a bis-ether compound by catalyzing benzaldehyde through mixed type heteropoly acid. Benzaldehyde and an alcohol compound are used as raw materials and mixed type heteropoly acid is used as a catalyst, so as to conduct reaction to prepare the bis-ether compound, wherein the alcohol compound is methanol, n-butanol or ethylene glycol, the molecular formula of mixed type heteropoly acid is H20[P8W60Ta12(H2O)4(OH)8O236].125H2O, and mixed type heteropoly acid is formed by one tetrameric Ta/W mixed type heteropoly anion, 20 protons and 125 crystal water molecules. Prepared mixed type heteropoly acid has the strongest acidity in heteropoly acid known at present, and has higher acid catalytic activity due to the strong acidity.
[Hmim]3PW12O40: A high-efficient and green catalyst for the acetalization of carbonyl compounds
Dai, Yan,Li, Bin Dong,Quan, Heng Dao,Lü, Chun Xu
experimental part, p. 678 - 681 (2011/10/31)
[Hmim]3PW12O40 was developed and used in the acetalization of carbonyl compounds in excellent yields. The ionic liquid-heteropoly acid hybrid compound and reaction medium formed temperature-dependent phase-separation system with the ease of product as well as catalyst separation. The catalyst was recycled more than 10 times without any apparent loss of catalytic activity.