54034-10-5Relevant academic research and scientific papers
Highly Efficient Oxidation of Secondary Alcohols to Ketones Catalyzed by Manganese Complexes of N4 Ligands with H2O2
Shen, Duyi,Miao, Chengxia,Xu, Daqian,Xia, Chungu,Sun, Wei
supporting information, p. 54 - 57 (2015/07/28)
The manganese complex Mn(S-PMB)(CF3SO3)2 was proven to be highly efficient in the catalytic oxidation of several benzylic and aliphatic secondary alcohols with H2O2 as the oxidant and acetic acid as the additive. A maximum turnover number of 4700 was achieved in the alcohol oxidation. In addition, the Hammett analysis unveiled the electrophilic nature of this manganese catalyst with N4 ligand. (Chemical Equation Presented).
Product selection through photon flux: Laser-specific lactone synthesis
Roscini, Claudio,Davies, David M. E.,Berry, Malcolm,Orr-Ewing, Andrew J.,Booker-Milburn, Kevin I.
scheme or table, p. 2283 - 2286 (2009/02/08)
(Chemical Equation Presented) Lasers flux their muscles: The Norrish type I and type II reactions of 1,3-indandiones can be controlled by judicious choice of light source. Selectivity depends on photon flux, not wavelength. Laser irradiation lead to lacto
