264-09-5Relevant academic research and scientific papers
Pyrolyse de dithiocarbonates aromatiques et du pentaerythrol
Kryczka, Boguslaw,Descotes, Gerard
, p. 475 - 482 (2007/10/02)
The thermolysis of dithiocarbonates derived from hydroxyphenols, aromatic glycols or pentaerythrol leads to elimination reactions, rearrangement or heterocyclization reactions according to their structures.
Stereochemistry of the Bicyclopentane Ringopening; Thermolysis of Tricyclo2,4>heptane Derivatives
Roth, Wolfgang R.,Klaerner, Frank-Gerit,Grimme, Wolfram,Koeser, Hans G.,Busch, Ralf,et al.
, p. 2717 - 2737 (2007/10/02)
Thermolysis of the anti-tricyclic compounds 6, 22 and 34 proceeds preferentially by concerted 2s+?2a>-reactions and leads to cis,trans-olefines 8, 24 and 37.The rearrangement of the syn-isomers on the other hand seems to be a nonconcerted reaction yielding the diradicals 15, 27 and 36.
PHOTOCHEMISTRY OF BENZOTRICYCLO2,7>HEPTENE: SINGLET EXCITED STATE REACTIONS DERIVED FROM CYCLOPROPANE RING CLEAVAGE
Johnson, Richard P.,Davis, Katherine Schlimgen
, p. 3171 - 3174 (2007/10/02)
Direct irradiation of the title hydrocarbon in cyclohexane affords 2-vinylindene and benzonorcaradiene as major primary photoproducts.Deuterium labeling is used to determine reaction mechanisms.
