54043-60-6

Basic information

• Product Name: 1,3,5-Triazine, hexahydro-1,3,5-tris(2-methylphenyl)-
• CAS NO: 54043-60-6
• Molecular Formula: C24H27N3
• Molecular Weight: 357.498
• Mol File: 54043-60-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,3,5-Triazine, hexahydro-1,3,5-tris(2-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Triazine, hexahydro-1,3,5-tris(2-methylphenyl)-(54043-60-6)
• EPA Substance Registry System: 1,3,5-Triazine, hexahydro-1,3,5-tris(2-methylphenyl)-(54043-60-6)

Safety Data

• Hazardous Substances Data: 54043-60-6(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 95-53-4 o-toluidine 
• 229323-97-1 2,2-dihydroperoxyadamantane 
• 88919-92-0 Methoxymethyl-o-tolyl-amine 

Downstream Products

• 183014-07-5 ethyl 1-(2-methylphenyl)-aziridine-2-carboxylate 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 121-33-5 vanillin 
• 1169473-44-2 diethyl 1,2,3,6-tetrahydro-1,3-di-o-tolylpyrimidine-4,5-dicarboxylate 
• 14683-79-5 (E)-2-methylbenzaldehyde oxime 
• 127459-91-0 (Z)-2-methylbenzaldoxime 
• 13362-80-6 4,8-dimethylquinoline 
• 611-21-2 N,2-dimethylaniline 

Relevant articles and documents

Efficient monomethylation synthesis method of aromatic primary amine

The invention relates to the field of organic synthesis, in particular to an efficient monomethylation synthesis method of aromatic primary amine. The method comprises the steps as follows: aromatic primary amine is used as a material to react with formaldehyde or paraformaldehyde, and a corresponding hexahydro-1,3,5-triaryl-1,3,5-triazine compound is obtained; the compound is subjected to catalytic hydrogenation under the action of a Pd/C catalyst, and a monomethylate of aromatic primary amine is obtained. The method has the greatest characteristics that the operation is simple, the conditionis mild, the raw material is cheap and easy to obtain, and the monomethylate of aromatic primary amine with high yield and high selectivity can be obtained. Posttreatment is simple, the production efficiency is improved, industrial mass production can be realized easily, and no equipment corrosion or environmental pollution can be caused.

Synthesis of N-substituted 1,3,5-triazacyclohexanes catalyzed by starch sulfuric acid

N-substituted 1,3,5-triazacyclohexanes were simply synthesized from the reaction of aromatic or fatty amines and formaldehyde catalyzed by recyclable starch sulfuric acid with good yields at room temperature.

Preparation of N,O-Aminals as Synthetic Equivalents of H2C=NAr and (H2C=NHAr)+ ions: Neutral- and Acid-promoted Transformations

A general method for the synthesis of N, O-aminals derived from primary aromatic amines is described.The reactivity of these compounds under neutral and acidic conditions has been studied and the title compounds can be envisaged as general purpose H2C=NAr or (H2C=NAr)+ equivalents.N,O-Aminals have been converted into perhydrotriazines by moderate heating and into bis(4-aminoaryl)methane derivatives or N-benzylarylamines, respectively, when heated in acidid media with pH control.Reduction od N,O-acetals with sodium cyanoborohydride has revealed that the C-O bond is broken exclusively in acidic media.