54100-46-8

Basic information

• Product Name: Phosphinic isothiocyanate, (1,1-dimethylethyl)phenyl-
• CAS NO: 54100-46-8
• Molecular Formula: C11H14NOPS
• Molecular Weight: 239.278
• Mol File: 54100-46-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphinic isothiocyanate, (1,1-dimethylethyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinic isothiocyanate, (1,1-dimethylethyl)phenyl-(54100-46-8)
• EPA Substance Registry System: Phosphinic isothiocyanate, (1,1-dimethylethyl)phenyl-(54100-46-8)

Safety Data

• Hazardous Substances Data: 54100-46-8(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 64578-97-8 Bis-disulfid 
• 54100-52-6 C₁₀H₁₄ClOPS 
• 54100-47-9 (R_p)-(+)-tert-Butylphenylphosphinothioic acid 
• 82945-12-8 (-)-S-t-butylphenyl-phosphinothiocyanidate 
• 54100-52-6 S-Chlor- 
• 97730-09-1 trimethylsilyl tert-butylphenylphosphinate 
• 75213-01-3 (S)-(-)-tert-butylphenylphosphinic chloride 
• 1147550-11-5 ammonium thiocyanate 
• 82220-43-7 tert-butylphenylphosphinic methanesulfonic anhydride 
• 54100-41-3 tert.Butyl(phenyl)phosphinothiocyanatidat 

Downstream Products

• 79157-92-9 C₁₁H₁₄NO₂P 
• 79157-99-6 C₁₁H₁₄Cl₂NOP 
• 79158-03-5 C₁₉H₂₅N₂OPS 

Relevant articles and documents

REACTION OF BIS-- AND BIS--DISULFIDES WITH TRIALKYLSILYLCYANIDES. NEW ROUTE TO DIALKYLPHOSPHORO- AND DIALKYLTHIOPHOSPHORO THIOCYANIDATES AND O,O,O,O-TETRAALKYLPYROPHOSPHOROTRITHIOATES

The reaction of organophosphorus disulfides with trialkylsilylcyanide has been investigated.It provided direct evidence for the intermediacy of thiocyanidate >P(X)SCN, X=O, S in this type of reaction.The disulfides studied involved phosphoryl, phosphonyl and/or phosphinyl disulfides.They have been shown to follow the common mechanism.The studied reaction of thiophosphoryl disulfides with trimethylsilylcyanide represents a new and highly efficient route to tetraalkylpyrophosphorotrithioates.

STEREOCHEMISTRY OF THE ACYCLIC PHOSPHONO- AND PHOSPHINO-THIOCYANIDE ISOMERISATION INTO CORRESPONDING ISOTHIOCYANIDATES SYNTHESIS OF OPTICALLY ACTIVE THIOCYANIDATES >P(O)SCN ISOTHIOCYANIDATES >P(O)NCS, ISOCYANIDATES >P(O)NCO AND RELATED PHOSPHORYLATED DERI

Optically active t-butylphenylphosphinothiocyanidate ButPhP(O)SCN 3 and t-butyl-O-methyl-phosphonothiocyanidate But(MeO)P(O)SCN 7 have been prepared by condensation of the corresponding sulphenyl chlorides >P(O)SCl with trimethylsily