54112-42-4Relevant academic research and scientific papers
Deamination Reactions, 49. - Decomposition of 2-Oxa-5- and -6-norbornanediazonium Ions
Kirmse, Wolfgang,Mrotzeck, Uwe
, p. 485 - 492 (2007/10/02)
The reactivity of 2-oxa-6-norbornanediazonium ions (19, 20) conforms to that of the analogous brosylates (7, 11).Photolysis of the tosylhydrazone 17 in aqueous sodium hydroxide yields 2-oxa-exo-6-norbornanol (15) with no endo isomer 22.The deuterium incor
Cyclit-Reaktionen, II. Darstellung von Bausteinen zur Synthese carbocyclischer Furanose-Analoga
Paulsen, Hans,Maass, Uwe
, p. 346 - 358 (2007/10/02)
The four isomeric hydroxycyclopentenmethanols 6a to 9a can easily be made by allylhydroxylation of the epoxides 2 and 4 with phenyl selenide.In a second way the pair 8a and 9a has been synthesized from 11 via 15.As the preparation of 20 demonstrates, the functionalisation of 6a to 9a to carbocyclic furanoses is possible.The dicarboxylic diethyl esters 23 and 33 can be converted into models for carbocyclic ketofuranoses.
