54166-92-6

Upstream product

• 79-37-8 oxalyl dichloride 
• 108-93-0 cyclohexanol 

Downstream Products

• 55695-93-7 Cyclohexyl-tert-butylperoxyglyoxalat 
• 54166-84-6 2'-Carbamoyl-3'-methoxyoxanilic acid cyclohexyl ester 
• 103698-37-9 2-{[2-cyclohexyl-1-(phenylsulfonyl)ethyl]sulfanyl}pyridine 
• 133616-24-7 3-Benzenesulfonyl-3-(pyridin-2-ylsulfanyl)-propionic acid cyclohexyl ester 
• 1233880-39-1 cyclohexyl 2-{3-[(2-chlorothiazol-5-yl)methyl]-2-(nitroimino)imidazolidin-1-yl}-2-oxoacetate 
• 1345971-13-2 cyclohexyl 2-(4-fluorophenyl)-2-oxoacetate 
• 1345971-14-3 cyclohexyl 2-oxo-2-(p-tolyl)acetate 
• 1018692-78-8 cyclohexyl 2-(4-methoxylphenyl)-2-oxoacetate 
• 1345971-11-0 cyclohexyl 2-(3,5-bistrifluoromethylphenyl)-2-oxoacetate 
• 1345971-32-5 cyclohexyl 2-(3,5-bistrifluoromethylphenyl)-2-(4-chlorophenyl)-2-hydroxyacetate 
• 1345971-30-3 cyclohexyl 2-(3,5-bistrifluoromethylphenyl)-2-hydroxyl-2-(3-methoxylphenyl)acetate 
• 1345971-28-9 cyclohexyl 2-hydroxy-2-(3,5-bistrifluoromethylphenyl)-2-(naphthalen-2-yl)acetate 
• 1345971-27-8 cyclohexyl 2-(3,5-bistrifluoromethylphenyl)-2-hydroxy-2-(4-phenyl-phenyl)acetate 
• 1345971-26-7 cyclohexyl 2-(3,5-bistrifluoromethylphenyl)-2-hydroxyphenylacetate 

Relevant academic research and scientific papers

Synthesis and application of oxalic acid monoester derivatives

The invention relates to synthesis and application of oxalic acid monoester-containing compounds as shown in a general formula (I) which is described in the specification. The compounds represent a broad-spectrum efficient insecticidal and bactericidal agent structure type. The oxalic acid monoester-containing compounds can well control aphids, plutella xylostella and spodoptera exigua when used as novel insecticidal bactericides; the compounds can also be used for preventing and treating cucumber brown blotch, cucumber bacterial angular leaf spot, cucumber fusarium wilt, cucumber downy mildew, cucumber powdery mildew, tomato bacterial leaf spot and rice sheath blight. R in the general formula (I) is as defined in the specification.

Chiral allene-containing phosphines in asymmetric catalysis

We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic ac

Design, synthesis and insecticidal activities of novel N-oxalyl derivatives of neonicotinoid compound

Ten novel neonicotinoid derivatives containing N-oxalyl groups were designed and synthesized, and their structures were characterized by 1H NMR, MS, IR, elemental analysis and single crystal X-ray diffraction analysis. The insecticidal activities of the new compounds were evaluated. The results of bioassays indicated that some of these title compounds exhibited excellent insecticidal activities.

Synthesis, crystal structure, and insecticidal activity of novel N-alkyloxyoxalyl derivatives of 2-arylpyrrole

Two series of novel N-alkyloxyoxalyl derivatives of 2-arylpyrrole were synthesized, and their structures were characterized by 1H NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction analysis. The insecticidal activities of the new compounds were evaluated. The results of bioassays indicated that some of these title compounds exhibited excellent insecticidal activities, and their insecticidal activities against oriental armyworm, mosquito, and spider mite are comparable to those of the commercialized Chlorfenapyr.

Reductive Addition to Electron-deficient Olefins with Trivalent Iodine Compounds

(Diacyloxyiodo)arene was treated with electron-deficient olefins in the presence of hydrogen donor such as 1,4-cyclohexadiene to give the reductive addition products via alkyl radical through the radical decarboxylative pathway in good yields.Moreover, this system was able to generate either alkoxycarbonyl radicals or alkyl radicals with benzene, which was prepared from alcohol, oxalyl chloride, and (diacetoxyiodo)benzene via two steps, depending on reaction conditions.These radicals were also utilized for C-C bond formation with electron-deficient olefins.

Conversion of Hydroxyl Groups in Alcohols to Other Functional Groups with N-Hydroxy-2-thiopyridone, and Its Application to Dialkylamines and Thiols

The radical decarboxylation reaction of N-alkoxyoxalyloxy-2-thiopyridone which was prepared by the reaction of alcohol, oxalyl chloride, and N-hydroxy-2-thiopyridone was studied both in the absence and presence of olefinic compounds.The same reactions with olefinic and acetylenic alcohols gave the corresponding lactone derivatives.On the other hand the unsymmetrical alkyl 2-pyridyl disulfides were obtained by the same reaction with aliphatic thiols.