54234-79-6

Basic information

• Product Name: Benzene, [(R)-propylsulfinyl]-
• CAS NO: 54234-79-6
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 54234-79-6.mol
• Article Data: 73

Chemical Properties

• CAS DataBase Reference: Benzene, [(R)-propylsulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(R)-propylsulfinyl]-(54234-79-6)
• EPA Substance Registry System: Benzene, [(R)-propylsulfinyl]-(54234-79-6)

Safety Data

• Hazardous Substances Data: 54234-79-6(Hazardous Substances Data)

Upstream product

• 429-41-4 tetrabutyl ammonium fluoride 
• 133957-59-2 2-(trimethylsilyl)ethyl benzenesulfenate 
• 107-08-4 1-iodo-propane 
• 7601-90-3 perchloric acid 
• 64-17-5 ethanol 
• 874-79-3 phenyl(propyl)sulfide 
• 7722-84-1 dihydrogen peroxide 
• 591-50-4 iodobenzene 
• 67653-00-3 (+/-)_S-(Z)-1-(phenylsulfinyl)prop-1-ene 
• 37605-46-2 (propa-1,2-diene-1-sulfinyl)benzene 
• 67652-99-7 (+/-)_S-(E)-1-(phenylsulfinyl)prop-1-ene 
• 1595-38-6 phenylthioallene 
• 1192-40-1 copper(I) thiophenolate 
• 7205-91-6 phenylthiomethyl chloride 

Downstream Products

• 104354-47-4 [(1-chloropropyl)sulfinyl]benzene 
• 1889-64-1 S-phenyl-S-propylsulfoximine 
• 13596-75-3 (propane-1-sulfonyl)-benzene 
• 874-79-3 phenyl(propyl)sulfide 

Relevant articles and documents

Aldehyde to Ketone Homologation Enabled by Improved Access to Thioalkyl Phosphonium Salts

Phosphines were previously unusable as Pummerer-type nucleophiles due to competing redox chemistry with sulfoxides. Here we circumvent this problem to achieve a formal phosphine Pummerer reaction that offers thioalkyl phosphonium salts that, in turn, give rise to diverse vinyl sulfides via Wittig olefinations. Thirty vinyl sulfides are thus prepared from (alkylthioalkyl)triphenyl phosphonium salts and aldehydes. The hydrolysis of these vinyl sulfides offers an efficient and versatile two-step one-carbon homologation of aldehydes to ketones.

An efficient heterogeneous Cu(I) complex for the catalytic oxidation of alcohols and sulfides: synthesis, characterization, and investigation of the catalyst activity

A heterogeneous Cu(I) complex was synthesized by reaction of C5H4NC(O)NHP(O)[NHC(CH3)3]2 (L) with CuCl and used as a catalyst for green oxidation of aromatic alcohols and sulfides. According to the characterization results obtained from 31P NMR, UV-Vis, FT-IR, mass, XRD, elemental analysis, and molar conductivity techniques, the chemical formula of the complex (1) was suggested as [CuClL2]. Parameters on the catalytic activity (reaction temperature, the substrate to oxidant molar ratio, catalyst amount, and solvent type) were optimized, using H2O2 as a green oxidant, and excellent conversion amounts (100%) were achieved under optimal conditions. Moreover, the generality and recyclability of the catalyst were tested and confirmed. A comparison between the oxidation results of the alcohol and sulfide in the presence of 1 with other catalysts indicated that in most cases 1 showed better efficiency, in a more reasonable reaction time and conditions.

Magnetic core-shell nanoparticle-supported Sc (III): A novel and robust Lewis acid nanocatalyst for the selective oxidation of sulfides to sulfoxides by H2O2 under solvent-free conditions

For the first time scandium triflate was supported on modified Fe3O4 magnetic nanoparticles [MNPs-PhSO3-Sc(OTf)2] and characterized using scanning electron microscopy (SEM), inductively coupled plasma analysis (