5424-77-1

Basic information

• Product Name: N-(9H-fluoren-9-yl)acetamide
• CAS NO: 5424-77-1
• Molecular Formula: C₁₅H₁₃NO
• Molecular Weight: 223.2698
• Mol File: 5424-77-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 463.4°C at 760 mmHg
• Flash Point: 277.3°C
• Density: 1.2g/cm³
• Vapor Pressure: 9.11E-09mmHg at 25°C
• Refractive Index: 1.643
• CAS DataBase Reference: N-(9H-fluoren-9-yl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(9H-fluoren-9-yl)acetamide(5424-77-1)
• EPA Substance Registry System: N-(9H-fluoren-9-yl)acetamide(5424-77-1)

Safety Data

• Hazardous Substances Data: 5424-77-1(Hazardous Substances Data)

Upstream product

• 1689-64-1 9-Fluorenol 
• 2157-52-0 9-fluorenone oxime 
• 64-19-7 acetic acid 
• 75-05-8 acetonitrile 
• 86-73-7 9H-fluorene 
• 82461-47-0 4-Methyl-benzenesulfinic acid (9H-fluoren-9-yl)-amide 
• 486-25-9 9-fluorenone 
• 100-46-9 benzylamine 
• 43133-20-6 9-fluorenyltrimethylstannane 
• 108-24-7 acetic anhydride 

Downstream Products

• 31551-45-8 2,7-dinitro-9-fluorenone 
• 14348-75-5 2,7-dibromofluorene-9-one 

Relevant articles and documents

A convenient protocol for C-H oxidation mediated by an azido radical culminating in Ritter-type amidation

Cerium(IV) ammonium nitrate in combination with sodium azide reacts with unactivated hydrocarbons in acetonitrile to furnish acetamides in one pot. The strategy can be used to introduce nitrogen functionality into a variety of compounds; a carboxylic ester directly afforded the corresponding α-amino acid.

PUMMERER-LIKE REACTION OF SULPHINAMIDES

Treatment of secondary sulphinamides (1), bearing one hydrogen atom at α-carbon to nitrogen, with electrophilic reagents leads in some cases to formation of N-sulphenylimines (2), via a Pummerer-like reaction.

Reactivity of organotin compounds. XIX. Reactions of organotin compounds with nitronium fluoroborate

The reactions of organotin compounds with nitronium fluoroborate were investigated.It was shown that nitronium fluoroborate is an oxidizing agent in relation to the compounds Me4Sn, Bu4Sn, (cyclo-C6H11)4Sn, and RSnMe3 (R=m-CH3C6H4, 9-fluorenyl, 9-methyl-9-fluorenyl), and the reaction products have radical nature.The reaction of nitronium fluoroborate with PhCCSnMe3 leads to the formation of oxidation and substitution products.