54248-06-5Relevant academic research and scientific papers
Activation of nitriles by metal ligand cooperation. reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design
Vogt, Matthias,Nerush, Alexander,Iron, Mark A.,Leitus, Gregory,Diskin-Posner, Yael,Shimon, Linda J. W.,Ben-David, Yehoshoa,Milstein, David
supporting information, p. 17004 - 17018 (2013/12/04)
The dearomatized complex cis-[Re(PNPtBu*)(CO)2] (4) undergoes cooperative activation of Ci - N triple bonds of nitriles via [1,3]-addition. Reversible C-C and Re-N bond formation in 4 was investigated in a combined experimental and c
Rhodium-Catalyzed Michael Additions of Activated Nitriles to α,β - Unsaturated Esters
Paganelli, Stefano,Schionato, Alberto,Botteghi, Carlo
, p. 2807 - 2810 (2007/10/02)
The Michael additions of activated nitriles to methyl acrylate (MA) and methyl vinyl ketone (MVK) proceeds with fair-to-high yields (46-92percent) in the presence of catalytic amount of HRh(CO)(PPh3)3 1 under mild reaction conditions.Key Words: Michael ad
