54263-85-3

Upstream product

• 5927-18-4 trimethyl phosphonoacetate 
• 589-92-4 1-methylcyclohexan-4-one 
• 77842-31-0 (4-methylcyclohexylidene)acetic acid 
• 74-88-4 methyl iodide 
• 86000-95-5 1-Methyl-4-((S)-4-methyl-cyclohexylmethanesulfinyl)-benzene 
• 23791-91-5 4-(bromomethyl)cyclohexylmethanol 
• 78507-26-3 trans-1-(bromomethyl)-4-methylcyclohexane 
• 3236-48-4 trans-1,4-Cyclohexanedimethanol 
• 127180-76-1 ethyl 4-methylcyclohexylideneacetate 
• 86000-98-8 (S)-(4-Methyl-cyclohexyl)-((S)-toluene-4-sulfinyl)-acetic acid methyl ester 
• 86000-98-8 (R)-(4-Methyl-cyclohexyl)-((S)-toluene-4-sulfinyl)-acetic acid methyl ester 

Downstream Products

• 13341-72-5 (+/-)-3,6-dimethyl-5,6,7,7a-tetrahydrobenzofuran-2(4H)-one 
• 13341-72-5 (+/-) isomintlactone 
• 31538-47-3 2-(4-Methyl-cyclohex-1-enyl)-propionic acid methyl ester 

Relevant academic research and scientific papers

Asymmetric Carboalkoxyalkylidenation with a Chiral Horner-Wadsworth-Emmons Reagent

The asymmetric carboalkoxyalkylidenation of 4-substituted cyclohexanones was effected by the use of chirally modified Horner-Wadsworth-Emmons (HWE) reagents in good yields (78-82percent) as well as high levels of enantioselectivity (78-86percent ee).

A versatile synthesis of butenolides: Total synthesis of (+/-)-mintlactone

The butenolide monoterpenes, mintlactone and isomintlactone, have been synthesized by a new method for the preparation of butenolides from α,β-unsaturated esters by deconjugation, epoxidation and rearrangement.