54265-10-0Relevant academic research and scientific papers
Trimethoxybenzene complexes of pentafluorophenylchlorocarbene
Wang, Lei,Moss, Robert A.,Krogh-Jespersen, Karsten
, p. 8113 - 8118 (2011/08/21)
Pentafluorophenylchlorocarbene, generated by laser flash photolysis (LFP) of pentafluorophenylchlorodiazirine, formed π-type complexes with 1,3,5-trimethoxybenzene in pentane. The carbene and carbene complexes were in equilibrium with K = 3.21 × 105
Pentafluorophenylhalocarbenes
Moss, Robert A.,Shen, Yongmaio,Wang, Lei,Krogh-Jespersen, Karsten
body text, p. 4752 - 4754 (2011/10/31)
Pentafluorophenylchlorocarbene and pentafluorophenylfluorocarbene are highly reactive species and effective carriers of fluorine labels via addition to alkenes and insertion into C-H bonds.
