54288-04-9Relevant academic research and scientific papers
Formation of α--Substituted Stable Enols and N,N-Dialkyldiarylacetamides from Diarylketenes and MeLi in HMPA
Nadler, Ella B.,Zipory, Elana S.,Rappoport, Zvi
, p. 4241 - 4246 (2007/10/02)
The reaction of an MeLi/HMPA mixture in ether with dimesityl- and mesitylphenylketene yielded the enols MesC(Ar)=C(OH)PO(NMe2)2 and MesC(Ar)=CHOH and the amides MesCH(Ar)CON(Me)R (Ar = Mes, Ph; R = Me, Et) together with other products.An initial cleavage
Stable Simple Enols. 5. Solvent Dependence of the Conformation of the OH Group in 2,2-Dimesitylethenol and Several 1,2,2-Triarylethenols
Biali, Silvio E.,Rappoport, Zvi
, p. 5641 - 5653 (2007/10/02)
3J(HCOH) and δ(OH) values of 2,2-dimesitylethenol (Mes2C=CHOH, 6) and δ(OH) values of five stable triarylethenols were measured in 12-14 solvents and found to be strongly solvent dependent. 3J(HCOH) values for 6 at 293 K decreased fr
