543740-55-2Relevant academic research and scientific papers
A terminal and four-coordinate titanium alkylidene prepared by oxidatively induced α-hydrogen abstraction
Basuli, Falguni,Bailey, Brad C.,Tomaszewski, John,Huffman, John C.,Mindiola, Daniel J.
, p. 6052 - 6053 (2003)
One-electron oxidation of the β-diketiminate titanium(III) bis-neopentyl complex (Nacnac)Ti(CH2tBu)2 (Nacnac = [Ar]NC(Me)CHC(Me)N[Ar], Ar = 2,6-(CHMe2)2C6H3) promotes α-abstraction to afford the rare and terminal four-coordinate neopentylidene (Nacnac)Ti=CHtBu(OTf), which was structurally characterized. Alkylidene (Nacnac)TiCHtBu(OTf) reacts cleanly with benzophenone and the imine functionality of the Nacnac ligand to afford the corresponding Wittig-type products. Copyright
