54377-34-3Relevant academic research and scientific papers
Preparative synthesis of (Z)-5-decenyl acetate
Chobanyan
, p. 2036 - 2037 (2004)
A procedure was developed for preparative synthesis of (Z)-5-decenyl acetate, the sex hormone of Agrotis Segetum.
Intramolecular Zinc-ene Reactions of Alkynes; Preparation of 1,5-Annulated 4-Methylenecyclopentenes
Louw, Jaap van der,Baan, Juul L. van der,Komen, Corine M. D.,Knol, Adri,Kanter, Franciscus J. J. de,et al.
, p. 6105 - 6122 (2007/10/02)
Intramolecular Type I zinc-ene reaction of 3-(alk-m-ynyl)-2-(methoxymethyl)-2-propenylzinc bromides 2 (m = 4,5,6) gave five-, six- and seven-membered carbometallation products 3, which on Pd(0)-catalyzed cyclization were converted to 1,5-annulated 4-methy
1,5-ANNELATED 4-METHYLENECYCLOPENTENES BY INTRAMOLECULAR TYPE I ZINC-ENErREACTIONS FOLLOWED BY Pd(O)-CATALYZED CYCLIZATION.
Louw, J. van der,Komen, C. M. D.,Knol, A.,Kanter, F. J. J. de,Baan, J. L. van der,et al.
, p. 4453 - 4456 (2007/10/02)
3-/Alk-m-ynyl)-2-(methoxymethyl)-2-propenylzinc bromides 1 (m=4,5,6) undergo intramolecular carbometallation.The products 2 were converted by Pd(O)-catalyzed cyclization to 1,5-annelated 4-methylenecyclopentenes 3.
