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67446-07-5

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67446-07-5 Usage

Uses

(5Z)-Decenyl Acetate is an insect sex pheromone semiochemical compound. Most abundant constituents in the oil of Heracleum crenatifolium.

Synthesis Reference(s)

Synthetic Communications, 20, p. 1339, 1990 DOI: 10.1080/00397919008052846

Check Digit Verification of cas no

The CAS Registry Mumber 67446-07-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,4,4 and 6 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 67446-07:
(7*6)+(6*7)+(5*4)+(4*4)+(3*6)+(2*0)+(1*7)=145
145 % 10 = 5
So 67446-07-5 is a valid CAS Registry Number.
InChI:InChI=1/C12H22O2/c1-3-4-5-6-7-8-9-10-11-14-12(2)13/h6-7H,3-5,8-11H2,1-2H3/b7-6-

67446-07-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Z-5-DECEN-1-YL ACETATE

1.2 Other means of identification

Product number -
Other names CIS-5-DECEN-1-YL ACETATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:67446-07-5 SDS

67446-07-5Downstream Products

67446-07-5Relevant articles and documents

Continuous Flow Z-Stereoselective Olefin Metathesis: Development and Applications in the Synthesis of Pheromones and Macrocyclic Odorant Molecules**

Browne, Duncan L.,Colombel-Rouen, Sophie,Crévisy, Christophe,Curbet, Idriss,Mauduit, Marc,McBride, Tom,Morvan, Jennifer,Roisnel, Thierry

supporting information, p. 19685 - 19690 (2021/08/06)

The first continuous flow Z-selective olefin metathesis process is reported. Key to realizing this process was the adequate choice of stereoselective catalysts combined with the design of an appropriate continuous reactor setup. The designed continuous process permits various self-, cross- and macro-ring-closing-metathesis reactions, delivering products in high selectivity and short residence times. This technique is exemplified by direct application to the preparation of a range of pheromones and macrocyclic odorant molecules and culminates in a telescoped Z-selective cross-metathesis/ Dieckmann cyclisation sequence to access (Z)-Civetone, incorporating a serial array of continually stirred tank reactors.

Stereoselective Alkyne Hydrogenation by using a Simple Iron Catalyst

Gregori, Bernhard J.,Schwarzhuber, Felix,P?llath, Simon,Zweck, Josef,Fritsch, Lorena,Schoch, Roland,Bauer, Matthias,Jacobi von Wangelin, Axel

, p. 3864 - 3870 (2019/07/31)

The stereoselective hydrogenation of alkynes constitutes one of the key approaches for the construction of stereodefined alkenes. The majority of conventional methods utilize noble and toxic metal catalysts. This study concerns a simple catalyst comprised of the commercial chemicals iron(II) acetylacetonate and diisobutylaluminum hydride, which enables the Z-selective semihydrogenation of alkynes under near ambient conditions (1–3 bar H2, 30 °C, 5 mol % [Fe]). Neither an elaborate catalyst preparation nor addition of ligands is required. Mechanistic studies (kinetic poisoning, X-ray absorption spectroscopy, TEM) strongly indicate the operation of small iron clusters and particle catalysts.

Production of pheromones and fragrances from substituted and unsubstituted 1-alken-3yl alkylates

-

Page/Page column 5, (2010/05/13)

Compounds of the formula (I) wherein R2 is a branched or unbranched, saturated or ethylenically mono or di unsaturated aliphatic radical, Z is —CH2OH, —CH2OAc or —CHO, m is a whole positive integer of one or more, and Ac is an acetyl group are synthesized by a process wherein a 1-alken-3-yl alkylate, is reacted with a halo alkanol Grignard reagent.

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