5441-16-7

Basic information

• Product Name: 1-ALLYLOXY-2,4-DICHLORO-BENZENE
• Synonyms: 1-ALLYLOXY-2,4-DICHLORO-BENZENE;ALLYL-2,4-DICHLOROPHENYL ETHER;2,4-dichloro-1-prop-2-enoxybenzene
• CAS NO: 5441-16-7
• Molecular Formula: C₉H₈Cl₂O
• Molecular Weight: 203.07
• Mol File: 5441-16-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 264.6°C at 760 mmHg
• Flash Point: 92.4°C
• Appearance: /
• Density: 1.227g/cm³
• Vapor Pressure: 0.0157mmHg at 25°C
• Refractive Index: 1.537
• CAS DataBase Reference: 1-ALLYLOXY-2,4-DICHLORO-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYLOXY-2,4-DICHLORO-BENZENE(5441-16-7)
• EPA Substance Registry System: 1-ALLYLOXY-2,4-DICHLORO-BENZENE(5441-16-7)

Safety Data

• Hazardous Substances Data: 5441-16-7(Hazardous Substances Data)

Usage

Physical state

Clear, colorless liquid

Odor

Sweet, fruity

Uses

Intermediate in production of pharmaceuticals, agrochemicals, and other organic compounds; solvent in industrial processes

Hazards

Harmful if swallowed, inhaled, or in contact with skin; may cause respiratory and skin irritation; harmful to aquatic life

Safety measures

Handle with caution and take proper precautions

InChI:InChI=1/C9H8Cl2O/c1-2-5-12-9-4-3-7(10)6-8(9)11/h2-4,6H,1,5H2

Upstream product

• 106-95-6 allyl bromide 
• 120-83-2 2,4-dichlorophenol 
• 3757-76-4 sodium 2,4-dichlorophenolate 
• 107-18-6 allyl alcohol 

Downstream Products

• 19182-95-7 3-(2-hydroxy-3,5-dichlorophenyl)prop-1-ene 
• 52234-92-1 (2,3-dibromo-propyl)-(2,4-dichloro-phenyl)-ether 
• 17944-27-3 (2,4-dichlorophenoxy)acetaldehyde 
• 205381-47-1 2,4-dichlorophenoxyethyl tetrahydro-2H-pyran-2-yl ether 
• 120-83-2 2,4-dichlorophenol 
• 60333-75-7 O-allyl-2-bromophenol 

Relevant articles and documents

Facile one-pot synthesis of aliphatic bridged diaryloxy compounds, cyclic and crown ethers under mild conditions

We report here the facile, room temperature, catalyst free, one pot synthesis of aliphatic bridged diaryloxy compounds, cyclic and crown ethers. Anhydrous potassium carbonate (K2CO3) as a mild base along with dimethyl sulfoxide gener

Thermodynamic, spectroscopic, and density functional theory studies of allyl aryl and prop-1-enyl aryl ethers. Part 1. Thermodynamic data of isomerization

A chemical equilibration study of the relative thermodynamic stabilities of seventy isomeric allyl aryl ethers (a) and (Z)-prop-1-enyl aryl ethers (b) in DMSO solution has been carried out. From the variation of the equilibrium constant with temperature the Gibbs energies, enthalpies, and entropies of isomerization at 298.15 K have been evaluated. Because of their low enthalpies, the (Z)-prop-1-enyl aryl ethers are strongly favored at equilibrium, the Gibbs energies of the a→b isomerization ranging from -12 to -23 kJ mol-1. The entropy contribution is negligible in most reactions, but occasionally small positive values less than +10 J K-1 mol-1 of the entropy of isomerization are found. The equilibration studies were also extended to involve two pairs of related isomeric ethers with a Me substituent on C(2) of the olefinic bond. The Me substituent was found to increase the relative thermodynamic stability of the allylic ethers by ca. 3.4 kJ mol-1.

Palladium-Catalyzed Etherification of Allyl Alcohols Using Phenols in the Presence of Titanium(IV) Isopropoxide

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