54423-73-3Relevant academic research and scientific papers
Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides
Gusarova, Nina K.,Sutyrina, Anastasiya O.,Kuimov, Vladimir A.,Malysheva, Svetlana F.,Belogorlova, Natalia A.,Volkov, Pavel A.,Trofimov, Boris A.
, p. 328 - 330 (2019/06/13)
Elemental phosphorus (red or white) reacts with alkyl bromides at 60–62 °C in the phase-transfer catalytic system KOH/H2O/PhMe/Et3BnNCl to afford alkyl-H-phosphinic acids in up to 47% yield.
REACTION BETWEEN 2-HYDROXY ESTERS OF HYPOPHOSPHOROUS ACID AND ALCOHOLS
Devedjiev, I.,Borisov, G.
, p. 37 - 42 (2007/10/02)
A study of the reaction between esters of hypophosphorous acid and alcohols is carried out.It has been established that the 2-hydroxy esters of hypophosphorous acid react with alcohols as a result of which phosphonous acids are formed.A possible scheme of this reaction is suggested.
