54459-01-7Relevant academic research and scientific papers
Regio- and enantioselective iridium-catalyzed allylation of thiophenol: Synthesis of enantiopure allyl phenyl sulfides
Zheng, Shengcai,Gao, Ning,Liu, Wei,Liu, Dongge,Zhao, Xiaoming,Cohen, Theodore
supporting information; experimental part, p. 4454 - 4457 (2010/11/19)
A highly regio- and enantioselective allylic alkylation of sodium thiophenoxide has been realized by [Ir(COD)Cl]2/phosphoramidite along with CsF as an additive, producing highly enantioenriched allyl phenyl sulfide compounds with up to 99% ee.
Investigations on the question of multiple mechanisms in the cope rearrangement
Wigfield,Feiner,Malbacho,Taymaz
, p. 2949 - 2959 (2007/10/12)
The possible occurrence of the ionic Cope rearrangement, and other non-concerted mechanisms is discussed. The synthesis of 2 - (1 - ethyl - 1 - propenyl) -2- (3 - p - methoxyphenylallyl)malononitrile (1b) and its clean thermal 1,3 rearrangement to (1 - et
