54535-06-7Relevant articles and documents
Mack et al.
, p. 7830,7831 (1976)
Macrocyclic bis-urea receptor: Synthesis, crystal structure and phosphate binding properties
Shu, Xi,Wang, Ruyu,Fan, Yu,Li, Shoujian,Huang, Chao
, p. 729 - 733 (2019/02/13)
A macrocyclic bis-urea receptor (L1) and two acyclic bis-urea analogues (L2 and L3) have been synthesized. The crystal structure of L1 was obtained. The experimental results show that the receptor L1 has high selectivity to H2PO4 ?. Meanwhile, compared with the acyclic receptors L2 and L3, L1 has higher binding ability to H2PO4 ?. The results of density functional theory (DFT) calculations deepened our understanding on L1 conformations stability and its anion-binding property.
Formation and uses of europium complexes
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, (2017/09/07)
The present invention provides a method of forming an oxidatively-stable aqueous Eu(II) complex by synthesizing ligands that coordinate to large, soft, electron rich metals like Eu(II). The invention also provides an oxidatively stable aqueous Eu(II) complex. The complex can be used for a variety of purposes some of which include, but are not limited to, in paramagnetic chemical exchange saturation transfer, as a medical diagnostic, as a semiconductor, and for use in forming materials.
Synthesis of monoazacrown ethers under phase-transfer catalysis
Luk'yanenko,Basok,Kulygina, E. Yu.,Bogashchenko, T. Yu.,Yakovenko
, p. 1345 - 1352 (2013/02/22)
A procedure has been proposed for the synthesis of monoazacrown ethers by reaction of N-benzyldiethanolamine with oligo(ethylene glycol) bis-p-toluenesulfonates in a two-phase system aromatic hydrocarbon-50% aqueous alkali, followed by removal of the benzyl group by catalytic hydrogenolysis. The maximal yields of N-benzylaza-12-crown-4, -18-crown-6, and -21-crown-7 were achieved by adding 4-10 equiv of LiCl, BaBr2, and CsCl, respectively, to the reaction mixture, which probably indicated template effect. Pleiades Publishing, Ltd., 2012.