54673-12-0

Basic information

• Product Name: Benzene, [2-(methoxymethoxy)ethyl]-
• CAS NO: 54673-12-0
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 54673-12-0.mol
• Article Data: 32

Chemical Properties

• CAS DataBase Reference: Benzene, [2-(methoxymethoxy)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-(methoxymethoxy)ethyl]-(54673-12-0)
• EPA Substance Registry System: Benzene, [2-(methoxymethoxy)ethyl]-(54673-12-0)

Safety Data

• Hazardous Substances Data: 54673-12-0(Hazardous Substances Data)

Upstream product

• 109-87-5 Dimethoxymethane 
• 82529-79-1 4-methoxybenzyl phenethyl ether 
• 60-12-8 2-phenylethanol 
• 13057-17-5 bromethyl methyl ether 
• 105104-40-3 Okahara's reagent 
• 107-30-2 chloromethyl methyl ether 
• 3587-61-9 1-chloromethyl 2-phenylethyl ether 
• 124-41-4 sodium methylate 
• 103-82-2 phenylacetic acid 

Downstream Products

• 493-05-0 isochromane 
• 60-12-8 2-phenylethanol 
• 103-45-7 acetic acid phenethyl ester 
• 17376-04-4 2-phenethyl iodide 
• 103-63-9 1-phenyl-2-bromoethane 
• 1355017-07-0 C₁₇H₁₄O 
• 1338236-26-2 C₁₇H₁₄O 
• 1338236-27-3 C₁₈H₁₆O 
• 1338236-28-4 C₁₈H₁₆O 
• 1338236-29-5 C₁₈H₁₆O 
• 1338236-30-8 C₁₉H₁₈O 
• 1338236-31-9 C₁₈H₁₃F₃O 
• 1338236-32-0 C₂₀H₁₈O₃ 
• 1338236-33-1 C₁₇H₁₃FO 

Relevant articles and documents

Ytterbium-Catalyzed Intramolecular [3 + 2] Cycloaddition based on Furan Dearomatization to Construct Fused Triazoles

The 1,2,3-triazole-containing polycyclic architecture widely exists in a broad spectrum of synthetic bioactive molecules, and the development of expeditious methods to synthesize these skeletons remains a challenging task. In this work, the catalytic cyclization of biomass-derived 2-furylcarbinols with an azide to form fused triazoles is described. This approach takes advantage of a single catalyst Yb(OTf)3 and operates via a furfuryl-cation-induced intramolecular [3 + 2] cycloaddition/furan ring-opening cascade.

Enantioselective synthesis of tetrahydroisoquinoline derivatives via chiral-at-metal rhodium complex catalyzed [3+2] cycloaddition

An asymmetric [3+2] cycloaddition of C,N-cyclic azomethine imines with α,β-unsaturated 2-acyl imidazoles catalyzed by a chiral-at-metal rhodium complex has been developed. The corresponding C-1-substituted tetrahydroisoquinoline derivatives were obtained in high yields (>90%) with excellent stereoselectivities (up to 99% ee and >20?:?1 dr). The reaction can be conducted on a gram-scale using a low catalyst loading (0.5 mol%) with high yield and selectivity.

Phosphane-Catalyzed [3+3] Annulation of C,N-Cyclic Azomethine Imines with Ynones: A Practical Method for Tricyclic Dinitrogen-Fused Heterocycles

A phosphane-catalyzed [3+3] annulation of azomethine imines with ynones has been developed. Under mild reaction conditions, the reaction proceeds smoothly to afford tricyclic dinitrogen-fused heterocyclic compounds in moderate to excellent yields with moderate to excellent stereoselectivies. Using a chiral phosphine as the catalyst, the reaction could work to give the cycloadduct in moderate yield with moderate enantioselectivity. (Figure presented.) .