5468-05-3Relevant academic research and scientific papers
Iodine-catalyzed tandem synthesis of terminal acetals and glycol mono esters from olefins
Kumar, Macharla Arun,Swamy, Peraka,Naresh, Mameda,Reddy, Marri Mahender,Rohitha, Chozhiyath Nappunni,Prabhakar, Sripadi,Sarma, Akella Venkata Subrahmanya,Kumar, Joseph Richard Prem,Narender, Nama
supporting information, p. 1711 - 1713 (2013/03/14)
A new metal-free protocol is described for the synthesis of terminal acetals by tandem oxidative rearrangement of olefins using oxone as an oxidant in the presence of iodine. Moreover, a one-pot procedure for the preparation of glycol mono esters from olefins is also presented for the first time using the same reagent system. The Royal Society of Chemistry 2013.
Non-acid catalytic acetalisation of aldehydes with diols in ionic liquids
Zhang, Fan,Xu, Dan-Qian,Luo, Shu-Ping,Liu, Bao-You,Du, Xiao-Hua,Xu, Zhen-Yuan
, p. 773 - 774 (2007/10/03)
The acetalisation of aldehydes with diols to corresponding 1,3-dioxolanes has been accomplished using ionic liquids as catalyst and reaction media. In the reaction process the removal of water produced and other catalysts were not necessary. High conversion and good selectivity were obtained when using HMImBF4, which could be easily recycled and reused.
Acetals by AlFe-pillared montmorillonite catalysis
Cramarossa, Maria Rita,Forti, Luca,Ghelfi, Franco
, p. 15889 - 15894 (2007/10/03)
AlFe-pillared montmorillonite is an efficient catalyst for acetals preparation in CH2Cl2 at room temperature.
A Simple and Efficient Conversion of Aldehyde Acetals into Esters
Sugai, Saburo,Kodama, Takashi,Akaboshi, Sanya,Ikegami, Shiro
, p. 99 - 105 (2007/10/02)
The reaction of aldehydic acetals with hypochlorous acid in acetic acid-acetone afforded the corresponding esters in excellent yields.From cyclic acetals, only the corresponding hydroxyalkyl esters were obtained.Keywords - acetal; hypochlorite; hypochlorous acid; conversion; ester; hydroxyalkyl ester; regioselectivity
