54722-12-2

Basic information

• Product Name: Phenylisopropylphosphine
• Synonyms: Isopropylphenylphosphine;Phenylisopropylphosphine
• CAS NO: 54722-12-2
• Molecular Formula: C₉H₁₃P
• Molecular Weight: 152.17
• Mol File: 54722-12-2.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Phenylisopropylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: Phenylisopropylphosphine(54722-12-2)
• EPA Substance Registry System: Phenylisopropylphosphine(54722-12-2)

Safety Data

• Hazardous Substances Data: 54722-12-2(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 75-26-3 isopropyl bromide 
• 644-97-3 Dichlorophenylphosphine 
• 172487-18-2 ethyl Phenylphosphinate 
• 63762-20-9 (±)-isopropyl(phenyl)phosphine oxide 
• 638-21-1 phenylphosphane 
• 6372-43-6 diisopropylphenylphosphane 
• 108-86-1 bromobenzene 
• 122427-83-2 isopropyl(trimethylsilyl)phosphine 
• 6372-40-3 isopropyldiphenylphosphine 

Downstream Products

• 565232-59-9 trihydro[isopropyl(phenyl)phosphine]boron 

Relevant articles and documents

Compound containing phosphine chiral center, organic transition metal complex and preparation method thereof

The invention provides a compound containing a phosphine chiral center, an organic transition metal complex and a preparation method thereof. The preparation method of the compound comprises the following steps: (1) reducing a secondary phosphine oxide 1 into a product secondary phosphine hydrogen 2 by using a reducing agent, wherein the reaction temperature is 20 to 100 DEG C, and the reaction time is 12 to 120 hours; and (2) adding alkyne and the secondary phosphine hydrogen prepared in the step (1) into an organic solvent by using a metal catalyst and a chiral ligand as catalysts to obtain the chiral phosphine compound. The synthesized chiral phosphine compound can be used as a ligand to directly react with transition metal salt to synthesize various organic transition metal complexes. According to the synthesis method disclosed by the invention, secondary phosphine oxide with good stability and low odor is used as a raw material, so that direct use of secondary phosphine with high toxicity and odor for reaction is avoided, and the chiral trivalent phosphine product and the derivative thereof are efficiently and selectively obtained.

Chiral Birch reduced tertiary phosphines: Precursors to asymmetric 1,2-cyclohexenebis(tertiary phosphines)

The first examples of an optically active Birch reduced tertiary phosphine, viz. (RP)-(cyclohexa-2,5-dienyl)(3-pentyl)phenylphosphine, and successful hydrophosphination of the related racemic ligand (±)- (cyclohexa-2,5-dienyl)(2-propyl)phenylph

Synthesis of electron-deficient secondary phosphine oxides and secondary phosphines: Bis[3,5bis(trifluoromethyl)phenyl]phosphine oxide and bis[3,5-bis(trifluoromethyl)phenyl]phosphine

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