54812-72-5

Basic information

• Product Name: Hexanedioic acid, monocyclohexyl ester
• Synonyms: Adipinsaeure-cyclohexylester;adipic acid monocyclohexyl ester;Mono-cyclohexyladipat;monocyclohexyl adipate;Adipinsaeure-monocyclohexylester;Hexanedioic acid,monocyclohexyl ester
• CAS NO: 54812-72-5
• Molecular Formula: C12H20O4
• Molecular Weight: 228.288
• Mol File: 54812-72-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Hexanedioic acid, monocyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanedioic acid, monocyclohexyl ester(54812-72-5)
• EPA Substance Registry System: Hexanedioic acid, monocyclohexyl ester(54812-72-5)

Safety Data

• Hazardous Substances Data: 54812-72-5(Hazardous Substances Data)

Upstream product

• 110-82-7 cyclohexane 
• 124-04-9 Adipic acid 
• 108-93-0 cyclohexanol 
• 5156-40-1 cyclohexyl nitrite 
• 2035-75-8 adipic anhydride 

Downstream Products

• 97002-31-8 Adipinsaeure-vinylester-cyclohexylester 
• 77357-98-3 cyclohexanol isooctyl adipate 

Relevant articles and documents

Assessment of formation channels of cyclohexyl mono- and dicarboxylates in oxidation of cyclohexane

Temperature dependences of the rate constants of the esterification reactions of the main carboxylic acids contained in oxidized cyclohexane (adipic, caproic, and formic) by cyclohexanol in a nonpolar medium were determined by solving the inverse kinetic problem.

Synergism of microwaves and immobilized enzyme catalysis in synthesis of adipic acid esters in nonaqueous media

Low-energy microwave irradiation leads to enhancement by a factor of up to 2.63 in comparison with conventional heating in immobilized lipase-catalyzed esterification of adipic acid with various alcohols and this effect is due to the greater frequency of collision, without any change in activation energy of the two modes of heating. Copyright Taylor & Francis, Inc.

SEQUENCE OF FORMATION OF PRODUCTS OF OXIDATIVE DECOMPOSITION OF CYCLOHEXANOL.

Oxidative decomposition of cyclohexanol by the action of molecular oxygen may be the consequence of various processes. One of these is consecutive conversion of the intermediately formed cyclohexanone. The main products in this case are the simultaneously formed adipic acid and epsilon -caprolactone and also, according to recent data, adipic anhydride. Another process involves radical decomposition of 1-hydroxy-1-hydroperoxycyclohexane, proceeding with cleavage of the C-C bond and formation (omitting the ketone stage) of adipic and caproic acids. However, it is most often assumed that formation of adipic acid during oxidation of cyclohexanol proceeds predominantly by the first route. The present work was undertaken in order to establish the relative significance, on the basis of the composition of the products of cyclohexanol oxidation, of the mechanisms, and to examine the possibility of influencing the course of the process.