5156-40-1Relevant articles and documents
A new synthesis of alkyl nitrites: The reaction of alkyl alcohols with nitric oxide in organic solvents
Grossi, Loris,Strazzari, Samantha
, p. 8076 - 8079 (1999)
In a nonaqueous solvent, alkyl nitrites can be easily achieved through the reaction of alkyl alcohols and gaseous NO. In the presence of air, the nitric oxide can in fact be oxidized to nitrous anhydride, which acts as a nitrosating agent. A quantitative
Direct cyclohexanone oxime synthesis: Via oxidation-oximization of cyclohexane with ammonium acetate
Peng, Ling,Liu, Chan,Li, Na,Zhong, Wenzhou,Mao, Liqiu,Kirk, Steven Robert,Yin, Dulin
supporting information, p. 1436 - 1439 (2020/02/11)
An unexpected cascade reaction for oxidation-oximization of cyclohexane with ammonium acetate was developed for the first time to access cyclohexanone oxime with 50.7% selectivity (13.6% conversion). Tetrahedral Ti sites in Ni-containing hollow titanium silicalite can serve as bifunctional catalytic centers in the reaction. This methodology not only provides a direct approach to prepare cyclohexanone oxime, but also simplifies process chemistry. Various available nitrogen sources, such as ammonium salt and even ammonia can be used as starting materials.
Novel and highly selective conversion of alcohols and thiols to alkyl nitrites with triphenylphosphine/2,3-dichloro-5,6-dicyanobenzoquinone/Bu 4NNO2 system
Akhlaghinia, Batool,Pourali, Ali Reza
, p. 1747 - 1749 (2007/10/03)
Alkyl nitrites were prepared in good to excellent yields by treatment of alcohols and thiols with triphenylphosphine/2,3-dichloro-5,6- dicyanobenzoquinone/Bu4NNO2 in acetonitrile. This method is highly selective for the conversion of primary alcohols to alkyl nitrites in the presence of secondary and tertiary alcohols and thiols.
