548490-06-8

Upstream product

• 55664-33-0 bis(tricyclohexylphosphine)platinum⁽⁰⁾ 
• 775-12-2 diphenylsilane 
• 807618-31-1 cis-Pt(tricyclohexylphosphine)2(H)(triphenylsilane(-1H)) 
• 807618-29-7 cis-Pt(tricyclohexylphosphine)2(H)(diphenylsilane(-1H)) 

Downstream Products

• 55664-33-0 bis(tricyclohexylphosphine)platinum⁽⁰⁾ 
• 548490-06-8 trans-Pt(tricyclohexylphosphine)2(H)(diphenylsilane(-1H)) 
• 807613-10-1 trans-Pt(tricyclohexylphosphine)2(H)(SiMe₂Cl) 
• 807618-34-4 trans-Pt(tricyclohexylphosphine)2(H)(SiCl₂Me) 
• 807618-35-5 trans-Pt(tricyclohexylphosphine)2(H)(SiCl₃) 
• 807613-05-4 cis-Pt(tricyclohexylphosphine)2(H)(SiMe₂CH₂CH=CH₂) 
• 807613-05-4 trans-Pt(tricyclohexylphosphine)2(H)(SiMe₂CH₂CH=CH₂) 
• 807613-00-9 cis-Pt(tricyclohexylphosphine)2(H)(SiEt₃) 
• 807613-07-6 cis-Pt(tricyclohexylphosphine)2(H)(Me₂SiOSiHMe₂) 
• 807613-09-8 cis-Pt(tricyclohexylphosphine)2(H)(Si(OMe)2CH₂CH=CH₂) 
• 807613-02-1 cis-Pt(tricyclohexylphosphine)2(H)[SiMe₂OCH₂C(Me)=CH₂] 
• 807613-08-7 cis-Pt(tricyclohexylphosphine)2(H)(SiMe(OSiMe₃)2) 
• 807618-31-1 cis-Pt(tricyclohexylphosphine)2(H)(triphenylsilane(-1H)) 
• 807613-03-2 trans-Pt(tricyclohexylphosphine)2(H)(triphenylsilane(-1H)) 

Relevant academic research and scientific papers

Platinum bis(tricyclohexylphosphine) silyl hydride complexes

A series of platinum metal silyl hydride complexes were prepared in solution by reaction of Pt(PCy3)2 with the appropriate silane, HSiR2R′. The complex was characterized using x ray crystallography at -100°C. The platinum center was found to exhibit a distorted-square-planar geometry with angles P(1)-Pt-P(2)=113.55(3)°, P(1)-Pt-Si=146.83(3)°, and P(2)-Pt-Si=99.37(3)°. The reaction of Pt(PCy3)2 with chlorinated hydrosilanes at -78°C was also found to yield analogues complexes which isomerized to their trans isomers on warming at room temperatures.