54884-84-3

Basic information

• Product Name: decane-5,6-diol
• Synonyms: decane-5,6-diol;5,6-Decanediol
• CAS NO: 54884-84-3
• Molecular Formula: C₁₀H₂₂O₂
• Molecular Weight: 174.28048
• EINECS: 259-384-5
• Mol File: 54884-84-3.mol
• Article Data: 34

Chemical Properties

• Boiling Point: 257.9°Cat760mmHg
• Flash Point: 135.5°C
• Appearance: /
• Density: 0.92g/cm³
• Vapor Pressure: 0.0021mmHg at 25°C
• Refractive Index: 1.454
• PKA: 14.32±0.20(Predicted)
• CAS DataBase Reference: decane-5,6-diol(CAS DataBase Reference)
• NIST Chemistry Reference: decane-5,6-diol(54884-84-3)
• EPA Substance Registry System: decane-5,6-diol(54884-84-3)

Safety Data

• Hazardous Substances Data: 54884-84-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H22O2/c1-3-5-7-9(11)10(12)8-6-4-2/h9-12H,3-8H2,1-2H3

Upstream product

• 19689-19-1 5-decene 
• 7433-78-5 cis-5-decene 
• 7433-56-9 (E)-5-decene 
• 50381-48-1 trioxo(N-tert-butylimido)osmium(VIII) 
• 1942-46-7 5-decyne 
• 110-62-3 pentanal 
• 109898-34-2 (S*)-1-((2R*,3R*)-3-propyloxiran-2-yl)pentan-1-ol 
• 131002-14-7 4,5-epoxy 5-fluoro decan-6-ol 
• 71-41-0 pentan-1-ol 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Site-Selective Mono-Oxidation of 1,2-Bis(boronates)

Site-selective oxidation of vicinal bis(boronates) is accomplished through the use of trimethylamine N-oxide in 1-butanol solvent. The reaction occurs with good efficiency and selectivity across a range of substrates, providing 2-hydro-1-boronic esters which are shown to be versatile intermediates in the synthesis of chiral building blocks.

Synthesis of heterodinuclear hemisalen complexes on a hexaarylbenzene scaffold and their application for the cross-pinacol coupling reaction

Intermolecular cross-pinacol coupling reaction between aliphatic and aromatic aldehydes by using heterodinuclear hemisalen complexes 1cis with vanadium(V) and titanium(IV) on a hexaarylbenzene scaffold is reported. Our ligand design is based on the individual activation of two aldehydes by vanadium and titanium, which are positioned with a suitable space on the rigid scaffold. Ligands such as 1cis were synthesized by Diels-Alder addition and decarbonylation reaction, followed by condensation of dialdehyde 3cis with various aminophenols. The influence of the substituents on the ligands on the pinacol coupling reaction was investigated. As a result, the reductive coupling reaction between aliphatic and aromatic aldehydes by using a catalytic amount of 1cis in the presence of Me3SiCl and Zn provided the corresponding cross-coupled 1,2-diol in good yields with high cross-selectivity. Working together: Dihemisalen ligands on a hexaaryl benzene scaffold were designed and the heterodinuclear complexes 1cis with vanadium(V) and titanium(IV) were synthesized from the corresponding disalicylaldehyde compound (see scheme). By using the heterodinuclear catalysts, the selective intermolecular cross-pinacol coupling reaction between aliphatic and aromatic aldehydes is demonstrated. Copyright

Homogeneous dihydroxylation of olefins catalyzed by OsO4 2- immobilized on a dendritic backbone with a tertiary nitrogen at its core position

OsO42- immobilized on a poly(benzyl ether) dendrimer with a tertiary nitrogen at its core position efficiently catalyzed the homogeneous dihydroxylation of olefins with a low level of osmium leaching. The dendritic osmium catalyst could be applied to the wide range of olefins. Furthermore, the dendritic osmium catalyst was recovered by reprecipitation and then reused up to five times.