54985-37-4Relevant academic research and scientific papers
Stereoselective Traceless Borylation–Allenation of Propargylic Epoxides: Dual Role of the Copper Catalyst
Jarava-Barrera, Carlos,Parra, Alejandro,Amenós, Laura,Arroyo, Ana,Tortosa, Mariola
, p. 17478 - 17481 (2017/11/30)
Chiral α-allenols are prepared with high diastereocontrol through an unprecedented and spontaneous β-oxygen elimination of an α-epoxy vinyl boronate. Stochiometric experiments and DFT calculations support a dual role of the copper catalyst, which orchestrates the hydroboration and the syn-elimination step.
Palladium-catalyzed arylation of allylic diols: Highly selective synthesis of phenyl-substituted allylic diols
Kang, Suk-Ku,Jung, Kyung-Yun,Park, Chan-Hee,Namkoong, Eun-Young,Kim, Tae-Hyun
, p. 6287 - 6290 (2007/10/02)
The coupling reaction of iodobenzene with allylic diols in the presence of Pd(OAc)2 and nBu3P as catalysts using K2CO3 as base afforded the phenyl-substituted allylic diols. However, under the same reaction conditions with Et3N as base, phenyl-substituted α-hydroxy ketone was obtained.
On the Transmetallation of (E)-1-Phenyl-3-(tributylstannyl)propene and 3-Phenyl-3-(tributylstannyl)propene with BuSnCl3
Miyake, Hideyoshi,Yamamura, Kimiaki
, p. 1473 - 1474 (2007/10/02)
Transmetallation of (E)-1-phenyl-3-(tributylstannyl)propene and 3-phenyl-3-(tributylstannyl)propene with BuSnCl3, and the isomerization of the transmetallated product are described.The application of the reactions to stereoselective (Z)-3-phenyl-2-propenylation and threo-1-phenyl-2-propenylation of aldehydes is also described.
REDUCTIVE COUPLING OF ALLYLIC ACETATES WITH CARBONYL COMPOUNDS BY USING Pd(O)-SmI2 SYSTEM
Tabuchi, Takanori,Inanaga, Junji,Yamaguchi, Masaru
, p. 1195 - 1196 (2007/10/02)
Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O) to yield homoallylic alcohols.
