5502-11-4

Upstream product

• 930-68-7 cyclohexenone 
• 38231-56-0 methyl 2-(1,4-dioxaspiro[4.5]dec-7-yl)acetate 
• 861924-46-1 2-(1,4-dioxaspiro[4.5]dec-7-yl)malonic acid dimethyl ester 
• 7076-70-2 2-(1,4-dioxaspiro[4.5]decan-7-yl)ethan-1-ol 
• 81415-36-3 2-(3-Oxo-cyclohexyl)-dithiomalonic acid di-S-ethyl ester 
• 66427-26-7 ethyl 2-(3-oxocyclohexyl)acetate 
• 190381-03-4 3-[2'-(allyldimethylsilyl)ethyl]cyclohexan-1-one 
• 33646-18-3 dimethyl 2-(3-oxocyclohexyl)malonate 

Downstream Products

• 943448-05-3 C₁₄H₂₈O₂Si 
• 943448-07-5 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one 
• 943448-06-4 C₁₇H₃₆O₂Si₂ 

Relevant academic research and scientific papers

An Approach to the Synthesis of Stenine

A type 2 N-acylnitroso intramolecular Diels-Alder reaction followed by reductive N - O bond cleavage formed the B and C rings of the Stemona alkaloid stenine. Further elaboration provided the functionalized tricyclic core.

Thiol esters in organic synthesis. X. A new approach to 1,5-ketols and 5-hydroxy esters using S,S'-diethyl dithiomalonate as an ethanol carbanion equivalent

Michael addition of S,S'-diethyl dithiomalonate to conjugated enones and α,β-unsaturated esters followed by reduction with Raney-nickel gave rise to 1,5-ketols and 5-hydroxy esters respectively in good yields.