55066-46-1

Upstream product

• 159028-45-2 3-methyl-5-phenylpent-1-yn-3-yl acetate 
• 55066-45-0 3-methyl-5-phenylpent-1-en-3-ol 
• 75-36-5 acetyl chloride 
• 2550-26-7 4-Phenyl-2-butanone 

Downstream Products

• 105273-60-7 1-(1-Methyl-1-phenethyl-allyl)-cyclohexanol 
• 105273-59-4 1-((E)-3-Methyl-5-phenyl-pent-2-enyl)-cyclohexanol 
• 76803-81-1 2-methyl-2-(2-phenylethyl)but-3-enoic acid 
• 1335229-23-6 N-(3-methyl-5-phenylpent-1-en-3-yl)aniline 

Relevant academic research and scientific papers

Ligand-controlled regiodivergent Ni-catalyzed reductive carboxylation of allyl esters with CO2

A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.

Copper-catalyzed Z-selective semihydrogenation of alkynes with hydrosilane: A convenient approach to cis-alkenes

A copper catalyst generated in situ from widely available copper salt and imidazolium salt in the presence of t-BuOK showed high efficiency for the semihydrogenation of a wide range of internal and terminal alkynes to their corresponding alkenes without obvious over-reduction. Functional groups, such as hydroxyl, nitro, halides, and amino, etc. were tolerated. The Z/E ratios of the obtained alkenes were generally >99%. Finally, semireduction of bulky alkynes also went smoothly.