55102-46-0

Upstream product

• 33647-67-5 1-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)ethanol from 2-Acetylfuran 
• 1192-62-7 1-(2-furyl)-1-ethanone 
• 4208-64-4 1-(2-furyl)ethanol 

Downstream Products

• 190504-61-1 (2S,3R,6R)-3-Benzyl-6-methoxy-2-methyl-3,6-dihydro-2H-pyran-3-ol 
• 5158-60-1 methyl 6-deoxy-3-O-methyl-α-L-mannopyranoside 
• 59531-21-4 methyl 4²-O-benzoyl-α-L-pillaroside 
• 1336914-68-1 C₁₀H₁₅FO₅ 
• 1336914-69-2 C₁₆H₂₀O₅S 
• 1336914-70-5 C₁₆H₂₀O₅S 
• 57918-22-6 4'-epi-N-(trifluoroacetyl)daunorubicin 
• 57918-24-8 4’-epidaunorubicin 
• 17016-64-7 methyl 3-benzamido-2,3,6-trideoxy-α-DL-lyxo-hexopyranoside 
• 32385-06-1 (+/-)-Ristosamine methyl ether 
• 62774-42-9 methyl 3-benzamido-4-O-benzoyl-2,3,6-trideoxy-α-DL-lyxo-hexopyranoside 
• 97327-50-9 methyl 4-O-(N-benzoylbenzimidoyl)-2,3,6-trideoxy-α-DL-threo-hex-2-enopyranoside 
• 97327-52-1 methyl 3-benzamido-4-O-benzoyl-2-bromo-2,3,6-trideoxy-α-DL-galactopyranoside 
• 34385-27-8 methyl 4-O-benzoyl-2,3,6-trideoxy-α-DL-threo-hex-2-enopyranoside 

Relevant academic research and scientific papers

SYNTHESIS OF (L)-DAUNOSAMINE AND RELATED AMINO SUGARS

1-(2-Furyl)ethanol (6) has been converted into methyl (+/-)-daunosaminide (1) and methyl (+/-)-ristosaminide (3) by use of an intramolecular cyclisation of a trichloroacetimidate group. (+/-)-Daunosamine (1) has been obtained more directly from the alcohol (10) by use of a modified Mitsunobu reaction; the scope of the latter reaction has been explored using cyclohex-2-en-1-ol as a model substrate.Asymmetric reduction of 2-acetylfuran (5) has given (S)-1-(2-furyl)ethanol (46) in good enantiomeric excess, thus providing a short route to the L-enantiomers of the amino sugars (1), (2), and (3) from a cheap, non-carbohydrate precursor.