59531-21-4

Upstream product

• 67786-42-9 (2S,3S,6R)-6-Methoxy-3-(1-methoxy-vinyl)-2-methyl-tetrahydro-pyran-3-ol 
• 59492-30-7 methyl (5S)-2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulose 
• 55102-46-0 methyl 2,3,6-trideoxy-α-L-glycero-hex-2-enopyranosid-4-ulose 
• 40246-38-6 methyl-2,3,6-tridesoxy-α-L-erythro-hex-2-enopyranoside 
• 25019-73-2 methyl α-L-amicetoside(methyl 2,3,6-trideoxy-α-L-erythro-hexopyranoside) 
• 98-88-4 benzoyl chloride 
• 67772-71-8 methyl α-L-pillaroside 

Relevant academic research and scientific papers

Branched-chain Sugars. Part 8. The Synthesis of C-Acetylpyranosides and a Pillarose Derivative using 1-Methoxyvinyl-lithium

1-Methoxyvinyl-lithium, a masked acylating agent, added to the protected hexopyranosiduloses (1), (4), and (7) to give adducts that were readily hydrolysed with acid to the C-acetyl derivatives (3), (6), and (9), respectively.The 1-methoxyvinyl adduct (13