55116-41-1Relevant academic research and scientific papers
SYNTHESIS OF α-AMIDOKETONES, AN APPLICATION OF THE MULTI-HETERO COPE REARRANGEMENT.
Lantos, Ivan,Zhang, wei-Yuan
, p. 5977 - 5980 (1994)
Condensation of ketone derived nitrones with N-methylcarboximidoyl chloride affords after hydrolytic workup α-amidoketones.The results are interpreted in terms of the formation of an intermediate capable of undergoing a facile sigmatropic rearrangement.Aldehyde derived nitrones form imides via a cycloaddition reaction. - Key words - Multihetero-Cope Rearrangement, Nitrones, α-Amido-ketones
