552848-77-8Relevant academic research and scientific papers
Pd-catalyzed ring-opening copolymerization of 2-aryl-1-methylenecyclopropanes with CO to afford polyketones via alternating insertion of the two monomers and C - C bond activation of the three-membered ring
Kim, Sunwook,Takeuchi, Daisuke,Osakada, Kohtaro
, p. 762 - 763 (2002)
Pd-bpy complexes catalyze the ring-opening copolymerization of 2-aryl-1-methylenecyclopropanes with CO, affording the new polyketones composed of ring-opened structural units only. Kinetic and isotope-labeling studies revealed the mechanism of the reactio
Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groups
Takeuchi, Daisuke,Osakada, Kohtaro
, p. 646 - 647 (2007/10/03)
π-Allyl-nickel complexes initiated addition polymerisation of 2-phenyl-1-methylenecyclopropane to give a polymer with three-membered rings; the formed polymer showed a high Tg and negligible thermal decomposition up to 300°C.
