55289-73-1

Basic information

• Product Name: N-(3-methylbut-2-en-1-yl)-4-nitrobenzamide
• Synonyms: N-(3-methylbut-2-en-1-yl)-4-nitrobenzamide
• CAS NO: 55289-73-1
• Molecular Weight: 234.255
• Mol File: 55289-73-1.mol

Chemical Properties

• CAS DataBase Reference: N-(3-methylbut-2-en-1-yl)-4-nitrobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-methylbut-2-en-1-yl)-4-nitrobenzamide(55289-73-1)
• EPA Substance Registry System: N-(3-methylbut-2-en-1-yl)-4-nitrobenzamide(55289-73-1)

Safety Data

• Hazardous Substances Data: 55289-73-1(Hazardous Substances Data)

Upstream product

• 26728-58-5 (3-methyl-2-butenyl)amine hydrochloride 
• 122-04-3 4-nitro-benzoyl chloride 
• 503-60-6 3,3-dimethyl-allyl chloride 

Downstream Products

• 67393-55-9 5-bromo-6,6-dimethyl-2-(4-nitro-phenyl)-5,6-dihydro-4H-[1,3]oxazine 

Relevant articles and documents

Highly Stereoselective Intermolecular Haloetherification and Haloesterification of Allyl Amides

An organocatalytic and highly regio-, diastereo-, and enantioselective intermolecular haloetherification and haloesterification reaction of allyl amides is reported. A variety of alkene substituents and substitution patterns are compatible with this chemistry. Notably, electronically unbiased alkene substrates exhibit exquisite regio- and diastereoselectivity for the title transformation. We also demonstrate that the same catalytic system can be used in both chlorination and bromination reactions of allyl amides with a variety of nucleophiles with little or no modification. A highly regioselective intermolecular haloetherification that proceeds with excellent enantioselectivity, catalyzed by cinchona alkaloid dimers, is reported. The regioselectivity is preserved for unbiased alkyl substituted allyl amides with either E or Z geometry. (DHQD)2PHAL=hydroquinidine 1,4-phthalazinediyl diether.