55305-15-2Relevant articles and documents
New method for the synthesis of pyrromethanes
Okada, Kunisuke,Saburi, Kiyoshi,Nomura, Keishi,Tanino, Hideo
, p. 2127 - 2131 (2007/10/03)
Coupling reaction of 2-mercaptobenzothiazolylmethylpyrrole with α-free pyrrole in the presence of silver(I) triflate proceeds smoothly at room temperature to give a pyrromethane in excellent yield. The azafulvenium ion, an active form that reacts with α-f
Reactions on solid supports part II: a convenient method for synthesis of pyrromethanes using a montmorillonite clay as catalyst
Jackson, Anthony H.,Pandey, Ravindra K.,Nagaraja Rao,Roberts, Edward
, p. 793 - 796 (2007/10/02)
α-Acetoxymethylpyrroles couple with α-free pyrroles in presence of Montmorillonite clay to form unsymmetrical pyrromethanes in excellent yields. Symmetrical pyrromethanes were also prepared in a similar manner by clay catalysed self-condensation of α-acet
SYNTHESIS OF UROPORPHYRIN-III, AND RELATED HEPTA- AND PENTA-CARBOXYLIC PORPHYRINS BY MODIFICATIONS OF THE MACDONALD METHOD
Chakrabarty, M.,Ali, S. A.,Philip, G.,Jackson, A. H.
, p. 1199 - 1204 (2007/10/02)
A modification of the MacDonald route has been developed in which all four pyrrole units of uroporphyrin-III have been derived from the same conveniently prepared starting pyrrole.Related hepta- and penta-carboxylic porphyrins have also been synthesised by condensation of appropriate α-formyl pyrromethane-α'-carboxylic acids; in each case other porphyrins with different numbers of acidic side-chains were also produced but the desired products were easily separated (as their methyl esters) by h.p.l.c.