55561-42-7Relevant academic research and scientific papers
AlCl3-N,N-DIMETHYLANILINE: A NEW BENZYL AND ALLYL ETHER CLEAVAGE REAGENT.
Akiyama, Takahiko,Hirofuji, Hajimu,Ozaki, Shoichiro
, p. 1321 - 1324 (1991)
Benzyl and allylethers have been cleaved readily on treatment with AlCl3 and N,N-dimethylaniline to give parent alcohols in high yields.Comparisons of N,N-dimethylaniline and anisole are also described.
A chemometric approach to map reaction media chemoselectivity: Example of selective debenzylation
Bensel, Nicolas,Klaer, Daniel,Catala, Cedric,Schneckenburger, Patrick,Hoonakker, Frank,Goncalves, Sylvie,Wagner, Alain
supporting information; experimental part, p. 2261 - 2264 (2010/07/10)
A chemometric process consisting in measuring the reactivity of a set of substrates under standardized and complementary reaction conditions was run to evaluate the possibility of building a coherent database that would give a general overview of the sele
Access to new steroids via a (1,2) Wittig rearrangement
Stephan, Elie,Dousset, Magali,Foy, Nicolas,Jaouen, Gerard
, p. 506 - 507 (2007/10/03)
Novel steroids are obtained by reaction of 9, 11-dehydro- dibenzylestradiol and dibenzylestradiol with phenyllithium in THF at room temperature.
AlCl3-N,N-Dimethylaniline: A Novel Benzyl and Allyl Ether Cleavage Reagent
Akiyama, Takahiko,Hirofuji, Hajimu,Ozaki, Shoichiro
, p. 1932 - 1938 (2007/10/02)
A combination system of AlCl3-N,N-dimethylaniline was found to cleave benzyl ethers readily to give parent alcohols in excellent yields.The system also cleaved allyl as well as methyl ethers.Numerous functional groups such as benzoyloxy, phenylthio, and olefinic double bond were not affected.Comparison of AlCl3-N,N-dimethylaniline and AlCl3-anisole were described.
