5557-93-7Relevant academic research and scientific papers
Time-resolved studies of the photogeneration and photochemistry of tetramethyl-o-xylylene
Wintgens,Netto-Ferreira,Casal,Scaiano
, p. 2363 - 2367 (1990)
The photodecomposition of 1,1,3,3-tetramethyl-2-indanone (V) leads to the formation of tetramethyl-o-xylylene (III), which ultimately decays to give o-isopropenylcumene (IV) as the only product. The xylylene III shows λmax ～ 358 nm in benzene a
Engineering reactions in crystals: Gem-dialkoxy substitution enables the photodecarbonylation of crystalline 2-indanone
Ng, Danny,Yang, Zhe,Garcia-Garibay, Miguel A.
, p. 7063 - 7066 (2002)
The photochemical reactivity of three 1,1,3,3-tetrasubstituted 2-indanones was investigated in solution and in crystals. While solution irradiation of tetramethyl-2-indanone 2 leads to 1-isopropenyl-2-isopropyl benzene 5 in high yield, crystals of 2 were
Nitric oxide cheletropic traps (NOCTs) with improved thermal stability and water solubility
Korth,Sustmann,Lommes,Paul,Ernst,De Groot,Hughes,Ingold
, p. 2767 - 2777 (2007/10/02)
The search for nitric oxide cheletropic traps (NOCTs) of the 7,7,8,8-tetraalkyl-o-quinodimethane type which would have properties appropriate for monitoring the formation of nitric oxide in cell cultures and in vivo by magnetic resonance techniques is des
Reactions of Oxasilacyclopropane. Generation of Silanediyl by Photo and Thermal Induced Cycloelimination
Ando, Wataru,Hamada, Yoshitaka,Sekiguchi, Akira
, p. 952 - 954 (2007/10/02)
Dimesitylsilanediyl was generated from photolysis and pyrolysis of the oxasilacyclopropane (1) via a 2 + 1> cycloelimination reaction.
