55591-27-0

Upstream product

• 1003-64-1 ethylidenecyclohexane 
• 64-19-7 acetic acid 
• 695-12-5 vinylcyclohexane 
• 76888-38-5 1-(1-cyclohexenyl)ethanol 
• 108-24-7 acetic anhydride 

Downstream Products

• 76888-38-5 1-(1-cyclohexenyl)ethanol 
• 61346-67-6 methyl 2-(2-ethylidenecyclohex-1-yl)acetate 
• 67428-38-0 methyl 3-(cyclohex-1-en-1-yl)butanoate 
• 67428-16-4 methyl 2-(methoxycarbonyl)-3-(1-cyclohexen-1-yl)butanoate 
• 67428-17-5 dimethyl 2-(2-ethylidenecyclohex-1-yl)malonate 
• 1371641-19-8 C₁₀H₁₆O₂ 
• 1371641-25-6 C₁₃H₂₄O₂Si 
• 1371641-32-5 C₁₃H₂₄O₂Si 

Relevant academic research and scientific papers

Regio- and stereoselectivity control in palladium-catalyzed allylic alkylation of 1-cycloalkenylmethyl acetates

Enantiomerically pure allylic acetates 1a and 1b were obtained by lipase-catalyzed acylation through kinetic resolution processes of the racemates. Palladium-catalyzed alkylation of 1a with dimethyl malonate was both regio- and stereoselective, showing th

Convenient and efficient Pd-catalyzed regioselective oxyfunctionalization of terminal olefins by using molecular oxygen as sole reoxidant

(Chemical Equation Presented) Just the one: The combination of palladium dichloride and N,N-dimethylacetamide (DMA) constitutes a highly efficient and reusable catalytic system, which uses molecular oxygen as the sole reoxidant for liquid-phase Wacker oxidation and acetoxylation of terminal olefins to the corresponding methyl ketones and linear allylic acetates, respectively (see scheme). 2006 Wiley-VCH Verlag GmbH Co. KGaA.

Preparation of Allylic Acetates from Simple Alkenes by Palladium(II)-Catalyzed Acetoxylation

The scope and limitations of palladium-catalyzed allylic acetoxylation has been investigated, using benzoquinone-manganese dioxide as the reoxidation system.Unsubstituted cycloalkenes gave good to excellent yields of allylic acetates.Total yields were also good for many substituted cycloalkenes and for linear alkenes, but these substrates generally gave several isomeric acetates.The exploratory mechanistic studies show that the acetoxylation can proceed via both 1,2-acetoxypalladation and η3-allylpalladium complex formation.The keen balance between these processes depends on the structure of the alkene.