55660-72-5

Upstream product

• 138-42-1 p-nitrobenzenesulfonic acid 
• 98-86-2 acetophenone 
• 54441-66-6 tert-butyl benzoylacetate 
• 6209-72-9 4-nitrobenzenesulfonyl peroxide 
• 61477-33-6 [hydroxy(p-nitrobenezenesulfonyloxy)iodo]benzene 
• 2206-94-2 1-acetoxy-1-phenylethene 
• 13735-81-4 1-styrenyloxytrimethylsilane 

Downstream Products

• 112537-89-0 4-Nitro-benzenesulfonate1-(2-oxo-2-phenyl-ethyl)-pyridinium; 
• 1816-88-2 2-azido-1-phenylethan-1-one 
• 20780-54-5 (S)-styrene oxide 
• 4636-16-2 iodoacetophenone 

Relevant academic research and scientific papers

Highly Efficient α-Organosulfonyloxylation of Carbonyl Compounds under Microwave Irradiation

Iodobenzene diacetate and organosulfonic acid mediated reaction of various carbonyl compounds under solventless microwave irradiation provided α-organosulfonyloxy carbonyl compounds in high yields.

An effective synthesis of α-azido ketones from ketones

One-pot transformation of ketones into α-azido ketones has been achieved by successive treatment with HNIB and NaN3 in acetonitrile.

Efficient method for α-iodination of ketones

α-Iodoketones are prepared in high yields from the initial reaction of various ketones with HNIB in CH3CN and subsequent treatment of potassium iodide or samarium(II) iodide.

Synthesis of α-Arylsulfonoxy Ketones from Ketone Derivatives

Silyl enol ethers, and enols can all be efficiently converted to α-arylsulfonoxy ketones by reaction with arylsulfonyl peroxides.