55682-13-8Relevant academic research and scientific papers
Pd(II) catalyzed ortho C-H iodination of phenylcarbamates at room temperature using cyclic hypervalent iodine reagents
Sun, Xiuyun,Yao, Xia,Zhang, Chao,Rao, Yu
supporting information, p. 10014 - 10017 (2015/06/22)
A novel approach to access ortho iodinated phenols using cyclic hypervalent iodine reagents through palladium(II) catalyzed C-H activation has been developed through weak coordination. The reaction showed excellent regioselectivity, reactivity and good functional group tolerance. A unique mechanism was proposed.
Palladium catalyzed C-H functionalization of O-arylcarbamates: Selective ortho -bromination using NBS
John, Alex,Nicholas, Kenneth M.
experimental part, p. 5600 - 5605 (2012/07/30)
A series of cyclometalated palladium complexes derived from O-phenylcarbamates has been synthesized by the reaction of the respective carbamates with Pd(OAc)2 in the presence of acids, CF 3CO2H, CF3SO3/sub
Suppressing the anionic fries rearrangement of aryl dialkylcarbamates; the isolation of a crystalline ortho-deprotonated carbamate
Garcia, Felipe,McPartlin, Mary,Morey, James V.,Nobuto, Daisuke,Kondo, Yoshinori,Naka, Hiroshi,Uchiyama, Masanobu,Wheatley, Andrew E. H.
, p. 644 - 647 (2008/09/17)
In the presence of organolithium bases phenyl dialkylcarbamates have previously been shown to undergo facile rearrangement to yield the corresponding salicylamides. However, heterometallic lithium diethyl(2,2,6,6- tetramethylpiperidido)zincate achieves th
